Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The compound, 1, was prepared via reacting the organolithium precursor with dichloro(p-tolyl)Stibine, 2 by chlorination of 1. Both 1 characterized multinuclear (1H, 13C 31P) NMR spectroscopy, their molecular structures resolved single-crystal X-ray diffraction. show a dative P−Sb interaction a...

considering the positive effects of silicon on salinity resistance by some agricultural plants, an investigation was conducted with a completely randomized design of three replications. the main objective was to determine the effect of silicon on nutrient content and nitrate accumulation in lettuce. electrical conductivity was adjusted at 3 mmhos/cm through addition of nacl. silicon was added t...

We report a mild method for generating the diphosphorus molecule or its synthetic equivalent in homogeneous solution; the P2 allotrope of the element phosphorus is normally obtained only under extreme conditions (for example, from P4 at 1100 kelvin). Diphosphorus is extruded from a niobium complex designed for this purpose and can be trapped efficiently by two equivalents of an organic diene to...

2-Phenoxy-1,3,2-diazaphospha-[3]ferrocenophane and related derivatives (oxide, sulfide, selenide) were prepared, characterized in solution by multinuclear magnetic resonance methods (1D and 2D 1H, 13C, 15N and 31P NMR) and in the solid state by X-ray structural analysis. The conformation of the 2-phenoxy derivative differs from that of the 2-tert-butyl compound. For further comparison, 2-R2,3-d...

The organo-phosphorus compound Dipterext (trichlorphon; OO-dimethyl-2,2,2,-trichlorethyl phosphonate) has attracted considerable attention during the past few years. Besides its use as an insecticide, an attempt has been made to employ this substance for the treatment of intestinal parasites (Beheyt, Lebrun, Cerf, Dierickx, and Degroote, 1961 ; Cerf, Lebrun, and Dierickx, 1962). Schistosomiasis...

A phosphorus containing dendrimer with a diphenylsilanediol core was synthesized using a divergent method. Several types of reactions were performed on dendrons of several sizes, either at the level of the core or the surface. The giant Schiff's base macro molecule possesses 12 imine bonds and 8 hydroxy groups on the terminal phenyl groups. The structures of the intermediate compounds were conf...

Z. Naturforsch. 54 b, 63-72 (1999); received August 3, 1998 Halfsandwich Compounds, Cycloheptatrienyl Complexes, Chromium, Tungsten, X-Ray Data A series of trinuclear carbonylmetal complexes of tri(l-cyclohepta-2,4,6-trienyl)phosphane, P(C? 1̂ 7)3 (1), has been prepared by the reaction of P(SiMe3)3 with ^-tropylium halfsand­ wich salts, [(7/7-C7H7)M(CO)3]BF4, (M = Cr, Mo, W). While phosphorus re...

The synthesis, spectroscopic characterization and X-ray crystal structure of a new chiral triosmium alkylidyne carbonyl cluster, (R,S)-[Os3(mu-H)2(CO)9{mu3-CPPh2(eta(5)-C5H4)Fe(eta(5)-C5H3(PPh2)CH(Me)NM(2)}] (1) are described. Compound 1 crystallizes in the non-centrosymmetric space group P2(1) and its absolute configuration has been established.The structure consists of an Os3C metal core with...

CaHPO4 was obtained by slow evaporation at room temperature. Seven samples, obtained at different annealing temperatures, were characterized by X-ray diffraction and 31P MAS-NMR spectroscopy. All NMR spectra were analyzed using a DMFIT program. At room temperature, the observed 31P NMR chemical shifts for the title compound were −1.59, −0.36 and 1.26 ppm with the relative intensities 39%, 10% a...