The separation of azeotropic mixtures has conventionally been one the most challenging tasks in industrial processes due to fact that components mixture will undergo gas–liquid phase transition at same time. We proposed a method for separating azeotropes using hydrate formation as solid–liquid transition. feasibility hydrate-based is determined by analyzing crystal structure and chemical bonds ...

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis), (2) temperature measurements that are true thermodynamic state points that can be modeled with an equation of state, (3) temper...

Complexation of a series of related amino compounds by 18-crown-6 ether (18C6) is studied as a means of improving the resolution of mixtures by combinations of ion mobility spectrometry (IMS) and mass spectrometry (MS) techniques. Mixtures of the isomeric amines n-octylamine (NOA), dibutylamine (DBA), and diisopropylethylamine (DIPEA) were electrosprayed to produce gaseous [M + H](+) ions. Thes...

This paper was selected for presentation by an SPE Program Committee following review of information contained in an abstract submitted by the author(s). Contents of the paper, as presented, have not been reviewed by the Society of Petroleum Engineers and are subject to correction by the author(s). The material, as presented, does not necessarily reflect any position of the Society of Petroleum...

Study of a mature petroleum play in the Western Canada Sedimentary Basin (WCSB) indicates that the spatial distribution of petroleum accumulations exhibits a self-affinity characteristic. This characteristic motivated the examination of a fractal model for a quantitative description of petroleum resource spatial distribution. The proposed approach transforms the spatial information with respect...

The health risk resulting from benzene exposure in petroleum refineries was calculated using data from the scientific literature from various countries throughout the world. The exposure data was collated into four scenarios from petroleum refinery environments and plotted as cumulative probability distributions (CPD) plots. Health risk was evaluated for each scenario using the Hazard Quotient ...

In Germany, the Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area (MAK Commission) generally sets maximum workplace concentration values (i.e., a proposed occupational exposure level [OEL]) for single substances, not for mixtures. For mixtures containing substances with a genotoxic and carcinogenic potential, the commission considered it scientifically in...

Inside living cells are complex mixtures of thousands of components. It is hopeless to try to characterize all the individual interactions in these mixtures. Thus, we develop a statistical approach to approximating them, and examine the conditions under which the mixtures phase separate. The approach approximates the matrix of second-virial coefficients of the mixture by a random matrix, and de...

Petroleum exploration and production is an industry that provides researchers with multi-variant challenging “real world” properties. Recently, some petroleum soft computing techniques have gained a greater interest in prediction within the oil industry. This paper is interested in the analysis, classifying, mining and predictions, based on fuzzy as an intelligent system and an intelligent syst...