Palladium-based catalyst can be employed for natural gas exhaust clean up due to its high activity for light hydrocarbon oxidation. Unfortunately, trace amounts of sulfur in the natural gas feed severely deactivate the catalyst. In this paper, SO2 adsorption over a monolithic Pd/Al2O3 oxidation catalyst is monitored in a time-resolved manner in the presence of 100 ppm SO2 under simulated aging ...

The selective oxidation of methoxy/methyl-substituted arenes to the corresponding benzoquinones has been first realized using aqueous hydrogen peroxide as a green oxidant, acid tetrabutylammonium salts of the γ-Keggin divanadium-substituted phosphotungstate [γ-PW10O38V2(μ-O)2]5- (I) as a catalyst, and MeCN as a solvent. The presence of the dioxovanadium core in the catalyst is crucial for the c...

Organometallic Ir precatalysts have been found to yield homogeneous Ir-based water-oxidation catalysts (WOCs) with very high activity. The Cp*Ir catalyst series can operate under a variety of regimes: it can either act as a homogeneous or a heterogeneous catalyst; it can be driven by chemical, photochemical, or electrochemical methods; and the molecular catalyst can either act in solution or su...

Designing oxidation catalysts based on CH activation with reduced, low oxidation state species is a seeming dilemma given the proclivity for catalyst deactivation by overoxidation. This dilemma has been recognized in the Shilov system where reduced Pt(II) is used to catalyze methane functionalization. Thus, it is generally accepted that key to replacing Pt(IV) in that system with more practical...

This paper remarks the general correlations of the shape and crystallinity of titanium dioxide (TiO₂) support on gold deposition and carbon monoxide (CO) oxidation. It was found that due to the larger rutile TiO₂ particles and thus the pore volume, the deposited gold particles tended to agglomerate, resulting in smaller catalyst surface area and limited gold loading, whilst anatase TiO₂ enabled...

Synthesis of complex tetraoxo-μ-oxobispentamethylpentacyclodienyl-dimolybdenum, Cp*2Mo2O5 was carried out in THF using Mo(CO)6 and NaCp* as starting materials. Oxidizing the intermediate, Na[Cp*Mo(CO)3], with 6 equivalent of TBHP under basic condition follow by acidification in aqueous resulting the product, Cp*2Mo2O5, was obtained in reasonable yield (42%). Characterizations of the synthesized...

Enhancing the surface binding stability of chromophores, catalysts, and chromophore-catalyst assemblies attached to metal oxide surfaces is an important element in furthering the development of dye sensitized solar cells, photoelectrosynthesis cells, and interfacial molecular catalysis. Phosphonate-derivatized catalysts and molecular assemblies provide a basis for sustained water oxidation on t...

Catalytic partial oxidation (CPO) of methane to syngas has received considerably interest recently as a way to utilize remote natural gas resources. Despite this interest, the mechanism of methane CPO is not completely understood. For example, there is disagreement in the literature if syngas is formed directly from oxidation or whether an indirect mechanism is responsible. Investigation of the...

a general overview on the prospective of various oxidation and combined processes in the treatment of tannery industry effluent are reported. various oxidation and combined processes such as uv/h2o2/hypochlorites, fenton and electro-oxidation, photo-chemical, photo-catalytic, electro-catalytic oxidation, wet air oxidation, ozonation, biological followed by ozone/uv/ h2o2, coagulation or ele...

In this study, aqueous solutions of 600 mg L of ammonia were oxidized in a trickle-bed reactor using Cu-activated carbon fiber (ACF) catalysts, which were prepared by incipient wet impregnation with aqueous solutions of copper nitrate that was deposited on ACF substrates. Experimental results showed that the total conversion efficiency of ammonia was 93% during wet oxidation over the catalyst a...