Hydrothermal pyrolysis experiments were performed to assess condensation (dehydration) reactions to amide, ester, and nitrile functionalities from lipid precursors. Beside product formation, organic compound alteration and stability were also evaluated. Mixtures of nonadecanoic acid, hexadecanedioic acid, or hexadecanamide with water, ammonium bicarbonate, and oxalic acid were heated at 300 deg...

Fruit including berries have been demonstrated to exhibit a broad spectrum of benefits including protection against cardiovascular, neurological, and lung diseases, as well as having antioxidant, antimicrobial, anti-inflammatory, antidiabetic and anti-aging properties. These protective effects are reported to be due to their high content of bioactive compounds, such as vitamin C, vitamin E, phe...

We deployed a high-resolution proton-transferreaction time-of-flight mass spectrometer (PTR-TOF-MS) to measure biomass-burning emissions from peat, crop residue, cooking fires, and many other fire types during the fourth Fire Lab at Missoula Experiment (FLAME-4) laboratory campaign. A combination of gas standard calibrations and composition sensitive, mass-dependent calibration curves was appli...

There is growing evidence that organo-nitrogen compounds may constitute a significant fraction of the aerosol nitrogen (N) budget. However, very little is known about the abundance and origin of this aerosol fraction. In this study, the concentration of organic nitrogen (ON) and major inorganic ions in PM2.5 aerosol were measured at the Duke Forest Research Facility near Chapel Hill, NC, during...

background and objectives: azotobacter is a diazotroph bacterium reported to possess various plant growth-promoting characteristics.the aim of this study was to isolate azotobacter strains capable of fixing nitrogen and effectively hydrolyzing both organic and inorganic pi compounds. materials and methods: in this study, soil samples collected from a diverse range of slightly alkaline soil type...

abstract this study was conducted under cold climate condition in khorasan during 2006-2008 growing seasons to evaluation of soil fertility in wheat-based double cropping systems under different rate of nitrogen and return of crop residues. a randomized complete block design with split-split plot arrangement and three replicates was used. main plots were five crop rotations namely: wheat-wheat,...

Nitrogen-containing heterocycles constitute an important division of organic chemistry. The structural and functional diversity in nitrogen-containing heterocyclic compounds emanates from the presence nature heteroatom that optimizes compound for a specific application. Nitrogen have been found to mimic various endogenous metabolites natural products, highlighting their pivotal role current dru...

Dissolved organic nitrogen (DON) is present in soils and streams around the world. We are only now beginning to explore the important roles this chemically heterogeneous mixture of compounds plays in terrestrial nitrogen (N) cycling. Over centuries, DON leaching may represent a significant "leak" of N, which occurs because plants and microbes cannot prevent DON losses, even in times of high N d...

indole is a nitrogen-containing heterocycle. it is a very important motif in agriculture and pharmacy. many compounds containing indole moiety has been isolated form nature. it is also an important part in natural alkaloids. tryptophan is an amino acid which posses indole. 3-sustituted indoles are the main group of its derivatives. because the wide-spread application of 3-substituted indolic co...