نتایج جستجو برای: optical rotation
تعداد نتایج: 333642 فیلتر نتایج به سال:
Both samples were then dialyzed versus demineralized water in the cold and aliquots withdrawn at intervals for viscosity and other measurements. After three hours, the viscosity of the control started to rise sharply, the value of [v ] reaching 24 in 24 hr. In contrast to this, the enzyme-treated sample showed no significant changes in either viscosity or rotation during the period of the dialy...
A short stereospecific synthesis of the carbocyclic 2 -deoxynucleoside analogues 36 and 37 (Schemes 2 and 5) and 45 and 46 (Schemes 2 and 6) starting from optically active 8,9,10-trinorborn-5-en-2-one (1) is described. As two functional groups capable to react with each other are present in the same molecule of the synthetic carbanucleosides, the latter can form polymers similar to oligonucleot...
We predict a new effect in electronic bilayers: spin Hall drag. The effect consists of the generation of spin accumulation across one layer by an electric current along the other layer. It arises from the combined action of spin-orbit and Coulomb interactions. Our theoretical analysis, based on the Boltzmann equation formalism, identifies two main contributions to the spin Hall drag resistivity...
The critical thermal maxima (CT(max)) of two sympatric, diurnal, thermophilic harvester ants from the Mojave Desert, USA (Pogonomyrmex rugosus and P. californicus) were measured by ramping their temperature upwards at a rate of 0.25 degrees C min(-1) during flow-through respirometry with optical activity detection. Rates of CO(2) emission ((CO(2))) increased exponentially to plateau values that...
We present an exhaustive account of phases and phase transitions that can be stabilized in the recently introduced generalized Lebwohl-Lasher model with quadrupolar and octupolar microscopic interactions [L. Longa, G. Pająk, and T. Wydro, Phys. Rev. E 79, 040701(R) (2009)]. A complete mean-field analysis of the model, along with Monte Carlo simulations allows us to identify four distinct classe...
The identification of a universal biosignature that could be sensed remotely is critical to the prospects for success in the search for life elsewhere in the universe. A candidate universal biosignature is homochirality, which is likely to be a generic property of all biochemical life. Because of the optical activity of chiral molecules, it has been hypothesized that this unique characteristic ...
We show that the inclusion of nonlocality in the constitutive relations in photonic structures has important repercussions in their eigenmode configuration and distribution. In the case of optical activity, the primary manifestation of nonlocality, these features are traced to a photospin-orbit interaction analogous to the electron spin-orbit interaction in asymmetric semiconducting compounds; ...
A light beam changes direction as it enters a liquid at an angle from another medium, such as air. Should the liquid contain molecules that lack mirror symmetry, then it has been predicted by Fresnel that the light beam will not only change direction, but will actually split into two separate beams with a small difference in the respective angles of refraction. Here we report the observation of...
A Co nanolayer is used as a local probe to evaluate the vertical inhomogeneous distribution of the electromagnetic (EM) field within a resonant metallic nanodisk. Taking advantage of the direct relation between the magneto-optical activity and the electromagnetic field intensity in the Co layer, it is shown that the nonuniform EM distribution within the nanodisk under plasmon resonant condition...
A vector-wave analysis of nondiffracting beams propagating along a birefringent chiral crystal for the case of tensor character of both the optical activity and linear birefringence is presented. We have written characteristic equations and found propagation constants and amplitude parameters of the eigenmodes. The characteristic curves have anomalous zones described by an isotropic point or a ...
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