Fuel flexibility is a significant advantage of solid oxide fuel cells (SOFCs) and can be attributed to their high operating temperature. Here we consider a direct internal reforming solid oxide fuel cell setup in which a separate fuel reformer is not required. We construct a multidimensional, detailed model of a planar solid oxide fuel cell, where mass transport in the fuel channel is modeled u...

Considering that natural gas is the key transition fuel towards carbon-neutral future, objective of present study to gain insight into evolution features gas-diesel dual during ignition process. Firstly, new experimental data delay times for stoichiometric methane/ethane/propane-n-heptane mixtures, which significance validating and optimizing chemical kinetic models at engine-relevant condition...

In the work, we mainly used molecular dynamics (MD) simulation and protein structure network (PSN) to study subtilisin Carlsberg (SC) immobilized onto carbon nanotube (CNT) in water, acetonitrile and heptane solvents, in order to explore activation mechanism of enzymes in non-aqueous media. The result indicates that the affinity of SC with CNT follows the decreasing order of water > acetonitril...

Dry reforming of methane for the production of hydrogen and syngas has attracted much attention from both industrial and environmental aspects. The major problem encountered in the application of this process is the rapid deactivation of the catalyst, which is mainly due to coke accumulation and sintering of the catalyst. As an alternative to reduce the coke formation, the combination of CO2 re...

Introduction Hydrogen as a fuel has recently been an important issue due to developments in fuel cell technology. Hydrogen production from sustainable sources, e.g. biomass, is gaining attention for a CO2 neutral energy supply. Recent developments in flash pyrolysis technologies make it possible to convert lignocellulosic biomass efficiently to a bio-oil, which is easier for handling and transp...

In this paper electrical conductivity measurements and optical investigations takes place in AOT/ heptane/ (water or aqueous) systems. The water in oil system prepared with adding water in 50% by weight of AOT/ heptane solution.  In other systems instead of water, aqueous solutions of 1) zinc acetate and water 2) Potassium Hydroxide and water were used. In each phase, the trend of the electrica...

The partial oxidation and CO2 reforming of methane were studied on Pt/Al2O3, Pt/ZrO2, and Pt/ Ce–ZrO2 catalysts. The reducibility and the oxygen transfer capacity were evaluated by oxygen storage capacity (OSC). The effect of the support on the cleaning mechanism of the catalyst surface was investigated by the sequence of CH4/O2 and CH4/CO2 pulses. The Pt/Ce–ZrO2 catalyst showed the highest sta...

Exploiting the greenhouse gas CO2 as raw material could be more advantageous than its long-term storage. For instance, CO2 can be used on large scale for the production of COrich syngas with a H2/CO ratio of unity. Such a syngas can be used for the synthesis of commodity chemicals like aldehydes and ketones obtained through carbonylation of alkenes in hydroformulation and can be produced by CO2...

Abnormal growth of population and development enormously increases energy demand. In present scenario utilization of fossils fuels to meet this demand is not enough and also leads to pollution, global warming, climate change as well as natural disaster. Therefore, hydrogen as energy carrier is a major option on these prospects as it is non-polluting and renewable. The renewable hydrogen energy ...

The measured dynamic surface tension of a water drop in air saturated by heptane vapor shows a sharp decrease from about 60 mN m−1 to 40 mN m−1, and less after a certain adsorption time. The observed adsorption kinetics is analyzed by a theoretical model based on multilayer adsorption of alkanes from the vapor phase at the water surface. The model assumes a dependence of the kinetic coefficient...