A research topic of current interest concerns the measurement and modeling adsorption isotherms water contaminants. The bulk measured equilibrium exhibit convex-upward or favorable curve shape, which can be described by two-parameter Hill-Langmuir Freundlich isotherms. An increasing number recent studies have however reported S-shaped sigmoidal Modeling such data requires use isotherm equations...

The kinetics and isotherm studies of the immobilized lipase and the mechanism of immobilization on chitosan beads and activated chitosan beads with glutaraldehyde were investigated. The effect of glutaraldehyde on porosity of chitosan was evaluated by FESEM analysis. It was observed that the porosity of the carrier which has activated by glutaraldehyde was substantially increased. The validity ...

liquid-phases adsorption equilibrium of phenol onto two naturally available soils namely kalathur soil (kr) and adhanur soil (ar) were studied. the experimental data were analyzed using fourteen isotherm models, ranging from single-parametric model to multi-parametric models (up to 5 parameters) of the system. results show that in general the accuracy of models to fit experimental data improves...

The purpose of this study is to investigate the capacity of natural Turkish zeolite for NH4-N removal from landfill leachate. The effects of modification and initial concentration on the removal of NH4-N from leachate were also investigated. The kinetics of adsorption of NH4-N has been discussed using three kinetic models, i.e., the pseudo-second order model, the Elovich equation, the intrapart...

Field ionization of trimethylamine and of N,N-dimethylaniline doped into xenon is presented as a function of xenon number density up to the density of the triple point liquid, both at noncritical temperatures and along the critical isotherm. These data exhibit a decrease in the xenon induced shift of the dopant ionization energy near the xenon critical point. The energy of the quasi-free electr...

The adsorption of methyl tert-butyl ether by granular activated carbon was investigated. The experimental data were analyzed using the Freundlich isotherm and the Langmuir isotherm. Although equilibrium data were found to follow Freundlich isotherm model, it were fitted better by the Langmuir model with a maximum adsorption capacity of 204.1 mg/g. The kinetic data obtained at different concentr...

A new method has been used to obtain pore size characteristics of MCM-41 catalyst supports and vanadiumsubstituted MCM-41 catalysts. The approach is based on the nonlocal density functional theory (NLDFT) model for nitrogen and argon adsorption in MCM-41, proposed recently. Samples with pore sizes varying from ca. 25 to 37 Å were prepared by hydrothermal synthesis. Two synthesis procedures empl...

The adsorption behavior of chlorendic acid (1, 4, 5, 6, 7, 7-hexachlorobicyclo-(2, 2, 1) -hept-5-ene-2, 3dicarboxylic acid) onto hydrophilic fumed TiO2 (P-25, Degussa) in aqueous suspension was investigated. Results indicate that chlorendic acid adsorbed strongly in short times (2-5 mins) onto TiO2. Adsorption data is consistent with LangmuirHinshelwood isotherm model for monolayer adsorption a...

In this paper, the sorption characteristics of aniline on Cr-bentonite prepared using synthetic wastewater containing chromium was investigated in a batch system at 30 degrees C. The effects of relevant parameters, such as pH value of solution, adsorbent dosage and initial aniline concentration were examined. The experimental data were analyzed by the Langmuir and Freundlich, and Temkin models ...