T he coupling of electron and proton transfer reactions is central to a broad range of biological and chemical processes, including photosynthesis, respiration, and various solar energy devices. Elucidation of the fundamental physical principles underlying proton-coupled electron transfer (PCET) reactions (1–5), in which both electrons and protons are transferred, is critical for a complete und...

Microorganims of the bovine rumen fluid biocatalyzed the reduction of nitro-compound substrates to yield the respective amines. This enzymatic process, using ruminal contents, has rarely been reported in association with the bioreduction of nitro groups. The biotransformation reactions catalyzed by this system were dependent of both the electronic characteristics and the area/volume of the nitr...

Same as Report (SAR) 18. NUMBER

The preparation of (hetero)arylamines has been significantly advanced by developments in transition metal-catalyzed Csp2–N coupling (e.g., Buchwald–Hartwig, Chan–Lam, and Ullmann couplings). As a complement to these strategies, our group recently demonstrated the reductive arylboronic acids nitro compounds, initially nitro(hetero)arenes more nitromethane, an organophosphorus-catalyzed method op...

A locally isolated Acinetobacter sp. Strain AQ5NOL 1 was encapsulated in gellan gum and its ability to degrade phenol was compared with the free cells. Optimal phenol degradation was achieved at gellan gum concentration of 0.75% (w/v), bead size of 3 mm diameter (estimated surface area of 28.26 mm(2)) and bead number of 300 per 100 ml medium. At phenol concentration of 100 mg l(-1), both free a...

The reaction of P-diketones 1 with phenyl hydrazine afforded 5-aryl-3-(1- methyl-5-nitro-2-imidazoly1)-1-phenylpyrazole (2) and 3-aryl-5-(1-methyl-5- nitro-2-imidazoly1) -1-phenylpyrazole (3). The reaction of diketones (1) with urea in the presence of p-toluenesulfonic acid gave 4-(or 6-)aryl-6-(or 4-)(1-methyl- 5-nitro-2-imidazolyl)-1-(lH)pyrimidones (4). The structures of all compounds w...