Using a general solvent-free procedure for the synthesis of chiral Schiff bases, the following compounds were synthesized and their crystal structures determined: (S)-(+)-2-{[(1-phenyl-eth-yl)imino]-meth-yl}naphthalene, C19H17N, (1), (S)-(+)-2-({[(4-methyl-phen-yl)eth-yl]imino}-meth-yl)naphthalene, C20H19N, (2), (R)-(-)-2-({[(4-meth-oxy-lphen-yl)eth-yl]imino}-meth-yl)naphthalene, C20H19NO, (3),...

The regulation of naphthalene and 1-naphthol metabolism in a Rhodococcus sp. (NCIMB 12038) has been investigated. The microorganism utilizes separate pathways for the degradation of these compounds, and they are regulated independently. Naphthalene metabolism was inducible, but not by salicylate, and 1-naphthol metabolism, although constitutive, was also repressed during growth on salicylate. T...

The aim of the current study was to investigate the potential of an aquatic plant, the water hyacinth (Eichhornia crassipes) devoid rhizospheric bacteria, to reduce naphthalene (a polyaromatic hydrocarbon) present in wastewater and wetlands. The capability of sterile water hyacinth plants to remove naphthalene from water and wastewater was studied in batch systems. Water hyacinths enhance the r...

The thermophilic aerobic bacterium Bacillus thermoleovorans Hamburg 2 grows at 60 degrees C on naphthalene as the sole source of carbon and energy. In batch cultures, an effective substrate degradation was observed. The carbon balance, including naphthalene, metabolites, biomass, and CO(2), was determined by the application of [1-(13)C]naphthalene. The incorporation of naphthalene-derived carbo...

3-Carbamoylmethyl-Indole-1-Carboxylic Acid Ethyl Ester (an ethoxycarbonyl derivative of indole-3-acetamide) is obtained by Friedel–Crafts type cyclocondensation γ-functionalized acetoacetamide in neat polyphosphoric acid.

Naphthalene (C10 H8) is a bicyclic aromatic hydrocarbon having 128 molecular weight [1]. Usually it is used as a deodorant in lavatories, moth repellent and as insecticides, mite powders and vermifuges [2]. In Bangladesh, a developing country, naphthalene is very popular and widely used moth repellent. People use it freely in household as it is very cheap and easily available. Naphthalene is ma...

The naphthalene dioxygenase enzyme system carries out the first step in the aerobic degradation of naphthalene by Pseudomonas sp. strain NCIB 9816-4. The crystal structure of naphthalene dioxygenase (B. Kauppi, K. Lee, E. Carredano, R. E. Parales, D. T. Gibson, H. Eklund, and S. Ramaswamy, Structure 6:571-586, 1998) indicates that aspartate 205 may provide the most direct route of electron tran...

Many cases of naphthalene and naphthalene poisoning are reported in literature since the introduction of naphthalene in 1841 by Rossbach as an internal antiseptic in typhoid fever and an anthelminthic in 1842. Today, naphthalene poisoning occurs in suicidal attenipts, or accidental ingestion by children. Naphthalene’s relative insolubility in water and its poor absorption from the gut underesti...

Acetamide (CH3CONH2) has been detected in emission and absorption toward the star-forming region Sagittarius B2(N) with the 100 m Green Bank Telescope (GBT) by means of four A-species and four E-species rotational transitions. All transitions have energy levels less than 10 K. The Sgr B2(N) cloud is known to have a cold halo with clumps of gas at several different velocities. Absorption feature...

Naphthalene (CAS Registry Number: 91-20-3) is a natural constituent of coal tar, comprising approximately 11% of that material by weight (HSDB, 2003). It is present in gasoline and diesel fuels. All pesticide registrations of naphthalene, including use as a moth repellent, were cancelled in California in 1991 due to data gap inadequacies. However, naphthalene is included on a list of "inert" or...