A diamine-bis(phenolate) chromium(III) complex, {CrCl[O2NN'](BuBu)}2 catalyzes the copolymerization of propylene oxide with carbon dioxide. The synthesis of this metal complex is straightforward and it can be obtained in high yields. This catalyst incorporates a tripodal amine-bis(phenolate) ligand, which differs from the salen or salan ligands typically used with Cr and Co complexes that have ...

Leather processing is an important industry in China, and the discharge of chromium waste has been severely circumscribed. Though traditional processes for treating chromium waste have been widely used in tannery plants, technology adopting high efficiency and economic simultaneously is deficient. In order to develop an economic treatment for tannery waste, a mixed alkali of sodium hydroxide an...

The demand for new, thermally conducting light weight and anti-corrosive materials is tried by incorporating Copper Oxide (CuO) nano powder in polyethylene matrix material. A laboratory level electro deposition technique is adopted here to prepare Copper Oxide (CuO) nano particles. Their phase composition is confirmed with X-Ray diffraction peaks and verified with standard JCPDS file for Copper...

to study the effects of nano-zinc oxide and seed inoculation with brady rhizobium and plant growth promoting rhizobacteria on yield and some agronomic traits of soybean, a factorial experiment based on randomized complete block design with three replications was conducted in 2013 at the research farm of the islamic azad university, ardabil branch. treatments were foliar application of nano-zinc...

Various pollutants (e.g. boron and hexavalent chromium) are introduced into the aquatic environment from a variety of industrial operations causing damages to environment and affecting human health. Boron in irrigation water is of particular interest because it can have beneficial or toxic effect on plants, depending on its concentration. Pollution of the environment with hexavalent chromium (C...

Chromium has two main valence states: hexavalent chromium (Cr[VI]) and trivalent chromium (Cr[III]). Cr(VI), a well-established human carcinogen, can enter cells by way of a sulfate/phosphate anion-transport system, and then be reduced to lower-valence intermediates consisting of pentavalent chromium (Cr[V]), tetravalent chromium (Cr[IV]) or Cr(III) via cellular reductants. These intermediates ...

Agro-waste materials such as sorghum straw (SS), oats straw (OS) and agave baggasse (AB) contain several functional groups (carboxyl, carbonyl, acetamido, amino, hydroxyl, etc.) which are able to bind heavy metal ions present in aqueous solution. The major advantages of these materials are: low-cost, high efficiency and regeneration. The agro-waste materials studied in this research (water wash...

silicon has useful effects on growth and yield of many plants. the aim of the present study is to investigate the impact of nano silicon oxide on proliferation and improvement of some growth traits of apple, cultivar gala. thus, an experiment was designed based on completely randomized design (crd) with five levels of nano silicon oxide concentrations (0, 25, 50, 100 & 200 ppm) in five replicat...

In this work the possibility of simultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys with help of the mixed organic reagents (diphenylcarbazide and 1,10-phenanthroline, diphenylcarbazide and sulphosalicylic acid) is studied. We have applied curve fitting method to separate individual signals of chromium (VI) and iron (III) from overlapped absorption spectrum. ...