[1] The correct representation of the 10-m drag coefficient for momentum (K10) at extreme wind speeds is very important for modeling the development of tropical depressions and may also be relevant to the understanding of other intense marine meteorological phenomena. We present a unified boundary layer model for (K10), which takes account of both the wave field and spray production, and asympt...

BACKGROUND Metalloporphyrin ions, with planar shape, have been known to intercalate horizontally and diagonally between montmorillonite layers. Perpendicular intercalation inside montmorillonite has not been reported earlier. This work aims at achieving perpendicular intercalation inside montmorillonite in natural clays. Possible intercalation inside other forms of natural clay will also be inv...

Animal feeding studies have demonstrated that clay additives, such as bentonites, can bind aflatoxins in ingested feed and reduce or eliminate the toxicity. Bentonite deposits are found throughout the world and mostly consist of expandable smectite minerals, such as montmorillonite. The surfaces of smectite minerals can be treated with organic compounds to create surface-modified clays that mor...

This paper studies the security of a recently-proposed chaos-based image encryption scheme, and points out the following problems: 1) there exist a number of invalid keys and weak keys, and some keys are partially equivalent for encryption/decryption; 2) given one chosen plain-image, a subkey K10 can be guessed with a smaller computational complexity than that of the simple brute-force attack; ...

Pyrolysis vapor upgrading can improve the stability of pyrolysis liquids to facilitate storage, transport, and drop in use as fuels chemical feedstocks existing refining infrastructure. This study investigates a low cost iron based catalyst for mild in-situ fast vapors increase liquid. Iron-doped montmorillonite K10 catalysts were characterized by ICP-OES, BET porosimetry, XRD, XPS, NH3-TPD. Th...

Hydrous amorphous Al (HAO), Fe (HFO), and Mn (HMO) oxides are ubiquitous in the subsurface as both discrete particles and coatings and exhibit a high affinity for heavy metal contaminants. To assess risks associated with heavy metals, such as Pb, to the surrounding environment and manage remedial activities requires accurate mechanistic models with well-defined transport parameters that represe...

The self-assembly of low molecular weight gelators confined within the nano-scale interlayer space of organo-montmorillonite is likely to be different from that under normal conditions (bulk space). Four kinds of gelators, 1-methyl-2,4-bis(N'-n-octadecylureido) benzene (MBB18), 1-methyl-2,4-bis(N'-n-dodecylureido)benzene (MBB12), bis(4'-stearamido phenyl) methane (BSM18) and bis(4'-octanamido p...

Surface modification of clay minerals has become increasingly important for optimizing the practical application of bentonites, kaolins, and clays. We describe the reaction of montmorillonite, an important mineral in bentonites, with cationic poly(ethylene oxides). Poly(ethylene oxides), PEOs, with molecular masses between 1550 and 35000, were modified by substituting the OH end groups by bromi...

oximes were oxidized to the corresponding carbonyl compounds in good to high yields by ecofriendlyand green oxidant, h202 catalyzed by montmorillonite k-10 supported mangenese(ii)chloride. the structures of these compounds were favorably compared with the results of ab initiocalculations at three temperatures. computational methods allow for the visualization of largeamounts of structural data ...

Adsorption of quinoline (pKa 5 4.92) and background electrolyte (CaCl2) onto specimen kaolinite and montmorillonite were measured as a function of pH (3–7.5) and ionic strength (1–10 mM), and as a function of quinoline concentration (0.2–1.55 mM) at fixed pH values of maximum adsorption. Maximum sorption of quinoline occurred at pH 3.5–4.0 for kaolinite, and pH 3.0–5.0 for montmorillonite. At t...