A PVC-based membrane containing cerium phosphate was developed. Unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. Therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. The response of molybdate selective electrode based on this membrane was perfectly linear in the concentr...

The decomposition of ammonium heptamolybdate was investigated by in situ XAFS and in situ XRD to elucidate the influence of different atmospheres on the products formed the formation of different decomposition products and various intermediates is described in detail.

The state of the electrochemical behaviour Al electrode in aqueous solutions containing Na2MoO4 + H3PO4 chitosan was investigated by methods currentless chronopotentiometry, chronoamperometry, optical and scanning electron microscopy. modification surface polymolybdate phosphate layers carried out a potentiostatic mode potentials range from ?1 to ?3 V polarization time (from 15 90 min). element...

Manganese reduction was catalyzed by enrichment cultures of anaerobic bacteria obtained from coastal marine sediments. In the absence of oxygen, these enrichment cultures reduced manganates when grown on either lactate, succinate, or acetate in both sulfate-free and sulfate-containing artificial seawaters. Sodium azide as well as oxygen completely inhibited microbial manganese reduction by thes...

Achromatium oxaliferum is a large, morphologically conspicuous, sediment-dwelling bacterium. The organism has yet to be cultured in the laboratory, and very little is known about its physiology. The presence of intracellular inclusions of calcite and sulfur have given rise to speculation that the bacterium is involved in the carbon and sulfur cycles in the sediments where it is found. Depth pro...

A molybdenum cofactor which is capable of reconstituting demolybdosulfite oxidase purified from livers of tungstentreated rats has been identified in rat liver and various organisms. Reconstitution with the rat liver cofactor is directly proportional to cofactor and demolybdoenzyme concentrations and proceeds most efficiently in 0.01 M potassium phosphate buffer, pH 7.4. The activation process ...

Estrogen receptors from rat uterus and human breast carcinoma were analyzed by diethylaminoethyl-cellulose chromatography. Cytosols which had been incubated for short periods of time demonstrated a single discrete elution peak, indicating a single ionic form, while cytosols incubated for longer periods of time generated a second ionic form of receptor. Addition of cations to cytosols also promo...

After La2Mo2O9 (LMO), Cu-substituted LMO (LCuMO), and CuMoO4 (CuMO) powders were prepared by complex polymerization method or oxide mixing method, their antiviral antifungal activities evaluated. The obtained samples having a crystal structure of either with specific surface area 3.0–6.0 m2/g. These exhibited almost equal activity against bacteriophage Qβ, whereas CuMO was found to have the hig...

Anabaena variabilis ATCC 29413 has two distinct nitrogenases that function in heterocysts, a conventional Mo-nitrogenase and an alternative V-nitrogenase. Synthesis of these two enzymes was repressed in cells growing with a source of fixed nitrogen, such as ammonium; however, the V-nitrogenase was also repressed by Mo. Expression of the V-nitrogenase which was not affected by V and expression o...

A molybdenum cofactor which is capable of reconstituting demolybdosulfite oxidase purified from livers of tungstentreated rats has been identified in rat liver and various organisms. Reconstitution with the rat liver cofactor is directly proportional to cofactor and demolybdoenzyme concentrations and proceeds most efficiently in 0.01 M potassium phosphate buffer, pH 7.4. The activation process ...