Zeolites containing Zn in their frameworks are promising materials for ion-exchange and catalysis because of their unique ion-exchange capabilities and characteristic Lewis acidity. However, expensive organic compounds often required in their synthesis can prevent their practical uses. Here, a facile organic-free synthesis route for new zincoaluminosilicate zeolites having MOR topology, in whic...

The catalytic activity of natural and synthetic zeolites modified by ion exchange with cations Ni2+, Zn2+, Cu2+, Co2+, Bi2+ Pd2+ in the reaction propylene oxidative conversion molecular oxygen to acrolein was studied. Based on experimental data, it found that clinoptilolite Ni2+ cation exhibits highest selectivity question. conditions were studied

The database of prospective zeolites (www. hypotheticalzeolites.net) has been screened in search of feasible zeolites. Previous criteria of zeolite feasibility have been reviewed, based on descriptors such as energy, density, average and distribution of ring sizes, and more importantly that of Li et al. (LID criteria) presented recently [Angew. Chem. Int. Ed. 2013, 52, 1673], based on Si–O, O.....

Surfactant-templating is one of the most versatile and useful techniques to implement mesoporous systems into solid materials. Various strategies based on various interactions between surfactants and solid precursors have been explored to produce new structures. Zeolites are invaluable as size- and shape-selective solid acid catalysts. Nevertheless, their micropores impose limitations on the ma...

The aim of this study was to prepare and characterize a potential drug support system based on surfactant/zeolite composites for anti-inflammatory drugs. In order to increase the adsorbing capacity the external surface of the natural zeolite clinoptilolite was modified with benzalkonium chloride in the treatments raging from 100% to 300% of the zeolite external cation exchange capacity. Adsorpt...

Crystals of zeolites with intricate micropores have been widely used in industry as heterogeneous catalysts, in particular as solid acid catalysts in the fields of oil refining and petrochemistry. However, relatively small individual micropores in zeolites such as Beta, ZSM-5, and Y strongly influence mass transport to and from the active sites located within them, severely limiting the perform...

Introduction and background: Zeolite minerals are hydrated framework aluminosilicates common to altered volcanic and volcanoclastic rocks, and the soils derived from them [1]. The mineralogy, chemistry, textural context, and abundance of zeolites provides insight into chemical weathering, hydrothermal, and metamorphic processes on Earth, in a variety of climates and tectonic settings. Zeolites ...

The development of accurate force fields is vital for predicting adsorption in porous materials. Previously, we introduced a first principles-based transferable force field for CO2 adsorption in siliceous zeolites (Fang et al., J. Phys. Chem. C, 2012, 116, 10692). In this study, we extend our approach to CO2 adsorption in cationic zeolites which possess more complex structures. Na-exchanged zeo...