The synthesis, characterization, and catalytic properties of 1-3 nm-diameter bimetallic PdAu dendrimer-encapsulated catalysts are reported. Both alloy and core/shell PdAu nanoparticles were prepared. The catalytic hydrogenation of allyl alcohol was significantly enhanced in the presence of the alloy and core/shell PdAu nanoparticles as compared to mixtures of single-metal nanoparticles.

We report a transient absorption study of photocarrier dynamics in transition metal dichalcogenide alloy, Mo0.5W0.5S2. Photocarriers were injected by a 400-nm pump pulse and detected by a 660-nm probe pulse. We observed a fast energy relaxation process of about 0.7 ps. The photocarrier lifetime is in the range of 50 - 100 ps, which weakly depends on the injected photocarrier density and is a fe...

Previous experiments have shown that tritium is produced in deuterated titanium. To better define the phenomenon a series of tests have been performed using various metals and alloys and different deuterating conditions. Sheets and shavings of titanium, zirconium, hafnium, tantalum, Zircaloy 2 and Ti-Zr 50% alloy have been tested. A statistical analysis of the tritium production shows that sign...

Hybridization-related modifications of the first metal layer of a metal-organic interface are difficult to access experimentally and have been largely neglected so far. Here, we study the influence of specific chemical bonds (as formed by the organic molecules CuPc and PTCDA) on a Pb-Ag surface alloy. We find that delocalized van der Waals or weak chemical π-type bonds are not strong enough to ...

Functional plating such as alloys or dispersion coatings have been widely used in metal finishing industry. In general, dispersion coatings are deposited from plating baths containing suspended particles such as metal oxides, carbides, metals or organic materials,(l-3) Codeposited particles in the dispersion coatings have the remarkable influence on the properties of the deposits depending on t...

A special form of laser spot welding is introduced to overlap dissimilar welding of titanium (G2) to 3105-O aluminum alloy. A welding tactile seam tracking design using following pulses that result to a circular seam leads to spot like shape laser welding. This technique was conducted to joint overlapped grad 2 Titanium alloy (Ti G2) to 3105-O Al alloy, with 1, and 0.5 mm thicknesses respective...

Dentists and technicians have used dental ceramics associated with different types of alloys without taking into account the characteristics of compatibility of these materials. Knowing the properties of the alloy and ceramic used in metal/ceramic restorations is a key factor for treatment success. The purpose of this study was to evaluate the bond strength of a palladium-silver alloy (Pors-on ...

BACKGROUND Resin-bonded fixed partial dentures appeared to prevent the excessive preparation of dental tissue. Investigation of surface treatments to improve the bond of resin cements to metals may contribute to the longevity of these restorations. Due to the potential lack of ideal preparation form, the type of alloy and its surface pretreatment may have clinically relevant correlations with t...

The prospect of extending existing metal-ceramic composites to those with the compositions that are far from thermodynamic equilibrium is examined. A current and pressure-assisted, rapid infiltration is proposed to fabricate composites, consisting of reactive metallic and ceramic phases with controlled microstructure and tunable properties. An aluminum (Al) alloy/Ti2AlC composite is selected as...