3.2 Enthalpies, entropies (solid and liquid state) – free energy and entropy of mixing The heats of formation of six solid Pb-Bi alloys have been measured at 400 K in a liquid lead solution calorimeter by P. Roy, et al. They found that these alloys obey Kopp’s law of additivity and the heats of formation are therefore temperature independent. The lead and bismuth used in these experiments were ...