Article history: Received January 01, 2012 Received in Revised form January 10, 2012 Accepted 13 January 2012 Available online 19 January 2012 In this paper complexation reaction between Yb3+ and Human serum albumin is examined using isothermal titration calorimetry (ITC). The extended solvation model was used to reproduce the enthalpies of HAS+Yb3+ interactions over the whole range of Yb3+ con...

ZrO2 is an attractive host matrix for luminescence material because of its excellent physical properties, such as low phonon energy and wide band gap. In this work, the highly transparent Tm2O3 Yb2O3 co-doped yttria stabilized zirconia (YSZ) (abbreviated Yb/Tm: YSZ) single crystals were grown by optical floating zone method. The YSZ samples in cubic phase at room temperature when Yb3+ Tm3+ repl...

Results of diode-pumped cw laser operation of an Yb3+:CaF2 single crystal are reported for what is to our knowledge the first time. With a 5-at.% Yb3+ -doped sample we obtained 5.8-W output power at 1053 nm for 15 W of incident power at 980 nm. The laser wavelength could be tuned from 1018 to 1072 nm, and a small-signal gain as high as 1.8 was achieved, showing the great potential of Yb3+:CaF2 ...

Tm3+-doped fiber is very suitable for producing ~2-μm laser emission due to its several unique advantages. First, Tm3+-doped fiber has a strong absorption spectrum that has good overlap with the emission spectrum of commercially available AlGaAs laser diodes. Second, the specific energy-level structure of Tm3+ ions provides the Tm3+-doped fiber laser (TDFL) quantum efficiency close to two throu...

Tm3+-doped fiber is very suitable for producing ~2-μm laser emission due to its several unique advantages. First, Tm3+-doped fiber has a strong absorption spectrum that has good overlap with the emission spectrum of commercially available AlGaAs laser diodes. Second, the specific energy-level structure of Tm3+ ions provides the Tm3+-doped fiber laser (TDFL) quantum efficiency close to two throu...

Core/shell (C/S)-structured upconversion nanophosphor (UCNP)-incorporated polymer waveguide-based flexible transparent displays are demonstrated. Bright green- and blue-emitting Li(Gd,Y)F4:Yb,Er and Li(Gd,Y)F4:Yb,Tm UCNPs are synthesized via solution chemical route. Their upconversion luminescence (UCL) intensities are enhanced by the formation of C/S structure with LiYF4 shell. The Li(Gd,Y)F4:...

Riboflavin (Rf) is a vitamin and endogenous photosensitizer capable to generate reactive oxygen species (ROS) under UV-blue irradiation and kill cancer cells, which are characterized by the enhanced uptake of Rf. We confirmed its phototoxicity on human breast adenocarcinoma cells SK-BR-3 preincubated with 30-μM Rf and irradiated with ultraviolet light, and proved that such Rf concentrations (60...

During the last decade inorganic luminescent nanoparticles that emit visible light under near infrared (NIR) excitation (in the biological window) have played a relevant role for high resolution imaging of cancer. Indeed, semiconductor quantum dots (QDs) and metal nanoparticles, mostly gold nanorods (GNRs), are already commercially available for this purpose. In this work we review the role whi...