نتایج جستجو برای: isocyanides

تعداد نتایج: 383  

Journal: :Dalton transactions 2014
Tatsuya Suzuki Yuji Kajita Hideki Masuda

A new iron complex with a thioamide SNS pincer type ligand, [FeBr2(κ(3)-H2L(DPM))] (κ(3)-H2L(DPM) = 2,6-bis(N-2,6-bis(diphenylmethyl)-4-isopropylphenylthioamide)pyridine), was synthesized. This complex reacts with NaH in THF to yield a unique Fe(ii) complex with two THF molecules, [Fe(THF)2(κ(3)-L(DPM))] (κ(3)-L(DPM) = 2,6-bis(N-2,6-bis(diphenylmethyl)-4-isopropylphenyliminothiolate)pyridine). ...

Journal: :Organic & biomolecular chemistry 2016
Zhijiang Zhang Bo Liu

Our previous total synthesis of the proposed structures of jiangrines C and D shows that the characteristic data of synthetic samples did not match those of the natural ones, prompting us to revise their structures. Accordingly, we now accomplished the total synthesis of jiangrines A, C and D, which confirms our deduction that their molecular skeletons should compose of 2,3-disubstituted pyrrol...

Journal: :Chemical communications 2005
Masao Tanabiki Kazuhiro Tsuchiya Yukihiro Motoyama Hideo Nagashima

The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

T3P/DMSO is shown to be an effective and mild reagent for the one-pot synthesis of furo[2,3-d]pyrimidine-2,4(1H,3H)-diones from a variety of alcohols. Alcohols are oxidized in situ to aldehydes under mild conditions, which undergo a three-component reaction with N,N'-dimethylbarbituric acid and various isocyanides to afford furo[2,3-d]pyrimidine-2,4(1H,3H)-diones in good yields.

2017
Ajay L Chandgude Alexander Dömling

The Ugi four-component reaction (U-4CR) with N-hydroxyimides as a novel carboxylic acid isostere has been reported. This reaction provides straightforward access to α-hydrazino amides. A broad range of aldehydes, amines, isocyanides and N-hydroxyimides were employed to give products in moderate to high yields. This reaction displays N-N bond formation by cyclic imide migration in the Ugi reacti...

Journal: :Chemical & pharmaceutical bulletin 2017
Ryosuke Saijo Hiroshi Sekiya Eiji Tamai Ken-Ichi Kurihara Jun Maki Hiroshi Sakagami Masami Kawase

In this report, we describe a new method for the synthesis of densely functionalized 2(1H)-pyrazinones. Treatment of mesoionic 1,3-oxazolium-5-olates with carbanions derived from activated methylene isocyanides (p-toluenesulfonylmethyl isocyanide (TosMIC) and ethyl isocyanoacetate) causes a novel ring transformation affording 2(1H)-pyrazinones in moderate to high yields. The cytotoxicity and an...

Journal: :Chemistry: A European Journal 2023

Isocyanides, thanks to their multiple reactivities, are the main players in multicomponent reactions. While traditional approaches exploit two-electrons reactivity, they currently “on stage”, shining a new light development of visible photochemical reaction conditions. For more information, see Review by Gian Cesare Tron and Mariateresa Giustiniano et al. (DOI: 10.1002/chem.202203150).

Elham Ahmadi Mohammad Mehdi Ghanbari, Pegah Mohagheghzadeh, Soheila Ghassamipoor

The reaction of stoichiometric amounts of dialkyl acetylenedicarboxylates with alkyl isocyanides and 5,5-diaryl thiohydantoins in toluene and catalytic amount of p-TSA afforded imidazo[2,1-b][1,3]thiazines in good overall yields

Journal: :organic chemistry research 2015
ali ramazani morteza rouhani sang woo joo

the synthesis of aryl amides via the reactions of carboxylic acids and isocyanides in methanol was carried out in 78-95% yields under ultrasound irradiation. the method has wide applicability, and the protocol is mild, fast and efficient compared to the existing methods based on silent conditions.

Journal: :organic chemistry research 0
morteza shiri alzahra university atefeh nejatinejhad-arani zeynab faghihi suhas a. shintre neil a. koorbanally

vilsmeier several diamide derivatives containing 2-chloroquinoline scaffolds were synthesized via ugi reaction of 2-chloroquinoline-3-carboxaldehydes, amines, carboxylic acids and isocyanides. the diversity of these quinolinyl ugi-adducts was increased by using 2-chloroquinoline-3-carboxylic acids as a source of acid. among them, compounds 2d, 2n, 2p, 4a, 4c and 4e displayed moderate to good an...

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