نتایج جستجو برای: isoconversional model
تعداد نتایج: 2104386 فیلتر نتایج به سال:
In this research, the thermal stability and decomposition kinetics of pentaerythritol tetranitrate (PETN) and Pentastite explosives have been studied experimentally using non-isothermal differential thermal analysis (DTA) and thermo-gravimetric (TG) methods at heating rates of 4.0, 6.0, 8.0 and 10.0 °C/min. The kinetic parameter of activation energy (Ea) and critical ignition temperature fo...
a semi-empirical mathematical model for predicting physical part of ignition delay period in the combustion of direct - injection diesel engines with swirl is developed . this model based on a single droplet evaporation model . the governing equations , namely , equations of droplet motion , heat and mass transfer were solved simultaneously using a rung-kutta step by step unmerical method . the...
Plastic pyrolysis is widely studied and implemented at lab-scale but rarely modelled numerically. For the sake of designing efficient industrial reactors, modelling plastic process particle scale could be a prerequisite. Therefore, aim this work to model whole process, on scale, for polypropylene (PP) high density polyethylene (HDPE) inside thermogravimetric analyzer coupled with differential s...
Abstract In this paper, films based on sustainable polymers with variable charge have been investigated by non-isothermal thermogravimetry in order to predict their lifetime, which is a key parameter for potential use numerous technological and biomedical applications. Specifically, chitosan has selected as positively charged biopolymer, while alginate chosen negatively biopolymer. Among non-io...
Kinetic Modeling of Ring-Opening Polymerization of Benzoxazines Using MIL-53-Al as a Potent Catalyst
In this study, we report the successful synthesis of a novel Al-based MOF/polybenzoxazine nanocomposite by facile and green approach via thermally induced ring-opening polymerization (ROP). Structural thermal characterization synthesized was accomplished using FTIR, XRD, BET TGA, DSC techniques, respectively. The Al-MOF showed catalytic activity in ROP good stability compared to non-catalyzed s...
A characteristic of granulated LTA and SOD zeolites is given. It was determined that zeolite particles have a cube shape with size ~2 μm; an irregular 0.5–1 μm. The dimension the coherent scattering region calculated to be 760 nm for 453 SOD. specific surface area 115 m2·g–1 141 m2·g–1. Static tests showed maximum quantity absorbed water vapor ~30 wt.%, ~20 wt.%. found provide adsorption from g...
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