Abstract Considering the importance of sub-monolayer transition metal oxides supported on another oxide in many industrial processes, with help a DFT + U approach, we provide information structural and electronic properties pure M 2 O 3 mixed MM ′O monolayers ( , ′ = Ti, V, Cr, Fe) an α -Al (0001) support. With their structure prolongation alumina corundum lattice, have non-equivalent surface i...

A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.

The co-extraction phenomenon was found in a typical chelate extraction system, in which the extraction of lanthanoid ion (Ln3+) with acetylacetone (Hacac) was highly enhanced by various metal ions (M(n+)) such as Cu2+, Al3+, and Zr4+. This phenomenon was ascribed to the formation of the 1:1 adduct between Ln(acac)3 and the M(acac),, extracted into the organic phase. The co-extraction occurred m...

In this study, a Multi-Objective Genetic Algorithm (MOGA) is utilized to extract interpretable and compact fuzzy rule bases for modeling nonlinear Multi-input Multi-output (MIMO) systems. In the process of non- linear system identi cation, structure selection, parameter estimation, model performance and model validation are important objectives. Furthermore, se- curing low-level and high-level ...