We aim to introduce photoactivated optical ion sensors based on a triggered ion exchange process as novel dynamic tools. The quantification of the acidity change upon photoactivation of spiropyran within an organic membrane phase during photoexcitation is described here for the first time, suggesting a large pK(a) change of more than 6 orders of magnitude.

Ion-exchange reactions are commonly used to develop novel metastable electrode materials for alkali-ion batteries that cannot be synthesized using direct chemical reactions. In this study, the electrochemical K Na ion-exchange reaction mechanisms in a layered KxCoO2 cathode as model system were investigated operando and ex situ structure characterization techniques. Some level of ions was obser...

H/D exchange is a method commonly used to probe molecular structure. The majority of studies in the gas phase have involved protonated molecular ions. The present study gives attention to molecular ions formed by coordination with a sodium ion. In particular, ND(3) is reacted with sodiated glycine oligomers, Gly(n)(), where n = 1-5, and the results are interpreted using density functional calcu...

Photocatalyst nanocomposites of ZnO/bentonite clay are synthesized by Solid-state ion exchange method. Ion exchange intercalation process of clays is used to incorporate the catalyst into the basal space of the layered structure of clays. The purpose of this study is to find a new method, which is focused on simplifying and saving time to prepare ZnO-bentonite composite with photocatalyst prope...

in this study, polystyrene ethylene butylene polystyrene (psebs) was functionalized to prepare mono and bipolar ion exchange membranes. in the case of the bipolar membrane, platinum was used as the intermediate layer. nacl solution of concentration ranging from 5 g/l to 25 g/l was used as the feed solution. a commercially procured ion exchange membrane made of polystyrene divinyl benzene was al...

The conformations of cytochrome c ions (+8 through +18) in the gas phase are examined by simultaneous ion-mobility and hydrogen-deuterium exchange measurements. By varying the voltage used to inject ions into the drift tube it is possible to study H/D exchange of specific conformers observed in the ion-mobility spectra: either very diffuse structures that are favored for all charge states at hi...

The gas-phase H/D exchange reactions of arginine (R) and arginine-containing di- and tri-peptide (gly-arg (GR), arg-gly (RG), gly-gly-arg (GGR), gly-arg-gly (GRG) and arg-gly-gly (RGG)) [M + H]+ ions with deuterated ammonia (ND3) were investigated by using Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR), ion mobility-mass spectrometry (IM-MS), ab initio and density function...