In industry, one of the main catalysts typically employed for the selective oxidation of methanol to formaldehyde is a multi-component oxide containing both bulk Fe2(MoO4)3 and excess MoO3. It is thought that the excess MoO3 primarily acts to replace any molybdenum lost through sublimation at elevated temperatures, therefore preventing the formation of an unselective Fe2O3 phase. With both oxid...

Incorporating deuteriums into the correct positions of organocatalysts increases their stability and robustness, just like story “The Three Little Pigs”: first two pigs hastily construct houses made straw sticks (non-deuterated dideuterated catalysts), but they were quickly destroyed by wolf′s huffing puffing (OH−). In contrast, third pig took time to build a sturdy house bricks (tetradeuterate...

seismic waves travelling through inelastic media are attenuated by the conversion of elastic energy into heat. upon being attenuated, the travelling wave changes: amplitude is reduced, travelling waveform is modified due to high-frequency content absorption, and phase is delayed. attenuation is usually quantified through the quality factor q: the ratio between the energy stored and lost in each...

The asymmetric transfer hydrogenation of imines was performed with the use of a polymer-immobilized chiral catalyst. The chiral catalyst, prepared from crosslinked polystyrene-immobilized chiral 1,2-diamine monosulfonamide, was effective in the asymmetric transfer hydrogenation of N-benzyl imines in CH(2)Cl(2) to give a chiral amine in high yield and good enantioselectivity. Furthermore, an amp...

The phenomenon of capillary condensation is studied through the weight change of condensed phase in an internally wetted porous pd catalyst pellet during the course of exothermic reacation of cyclohexane hydrogenation in a thermogravimetric analyzer (TGA). The direct measurement of condensed phase indicates that evaporation of condensed phase is confined to the macropores of catalyst pellet at ...