Nanostructures exhibit numerous merits to improve the efficiency in solar-to-energy conversion. These include shortened carrier collection pathways, an increased volume ratio between depletion layer and bulk, enhanced light capture due to multiple light scattering in nanostructures, and a high surface area for photochemical conversion reactions. In this study, we describe the synthesis of morph...

The kinetic of the heterogeneous chemical reaction of aluminum hydroxide and fluosilicic acid was studied. It was found that the diffusion of the reactants through the porous silica coating to the aluminum hydroxide surface and the interfacial chemical reaction between the diffusing reactant and aluminum hydroxide platelets control the overall reaction rate. These two phenomena were studied...

Surfactant miscible-displacement experiments represent a conventional means of estimating air-water interfacial area (A(I)) in unsaturated porous media. However, changes in surface tension during the experiment can potentially induce unsaturated flow, thereby altering interfacial areas and violating several fundamental method assumptions, including that of steady-state flow. In this work, the m...

While the structure and dynamics of boundary layers on rigid no-slip walls in rotation dominated enclosed flows are still an area of active research, the interactions between rotating or swirling flows with a free surface have received comparatively less attention. For the most part, investigations in this area have been focused on clean free surfaces, which may be treated as stress-free. Howev...

The preparation and characterization of high-surface-area polymeric substrates suitable for the microcalorimetry of protein adsorption are described. High-surface-area polystyrene, poly(styrene-co-butyl methacrylate) and poly(styrene-co-allyl alcohol) were prepared by adsorbing polymer from solution onto fumed silica. Verification of adsorption of polystyrene by silica was determined by noting ...

The solid particles are adsorbed at interfaces and form self-assembled structures when the particles have suitable wettability to both liquids. Here, we show theoretically how the microstructure on the particle surface affects their adsorption properties. The physical properties of the interface adsorbing a particle will be described by taking into account the surface roughness due to the micro...

Low-energy forward-recoil spectrometry studies show that the interface between polystyrene sAd and a miscible blend of two poly(styrene-co-4-bromostyrene)s sB:Cd has an interfacial excess of B, z B, where B is the component with the lower bromostyrene level. At 170 ±C, z B increases with the bulk volume fraction of B, fB`, has a maximum near 0.25, and then decreases. These results are in qualit...