Accumulation and Release of Trace Inorganic Contaminants from Biofilm Matrices Developed and Challenged under Drinking Water Distribution System Conditions by William W. Kent, Master of Science Utah State University, 2016 Major Professor: Joan McLean Department: Civil and Environmental Engineering Over the legacy time frames experienced by drinking water distribution systems (DWDS), trace inorg...

Mixed-matrix membranes based on amorphous and semi-crystalline polyimides with zirconium dioxide (ZrO2) nanostars were synthesized. Amorphous poly(4,4′-oxydiphenylenepyromellitimide) and semi-crystalline polyimide prepared from 1,4-bis(4-aminophenoxy)benzene and 4,4’-oxydiphthalic anhydride were used. The effect of ZrO2 nanostars on the structure and morphology of nanocomposite membranes was st...

NiTi wires were functionalized with silane coupling agents to improve interfacial adhesion between the inorganic constituent and a host matrix for composite applications. Surface derivatization was characterized by X-ray Photoelectron Spectroscopy, and mechanical pullout tests were performed to quantify the increase in adhesion between the NiTi shape memory alloy wires and polymer matrix. Impro...

We investigate the influence of interfacial treatment on the matrix-filler interaction using a meltmixing process to fabricate robust and highly stretchable dielectrics. Silicone oil and silane coupling agent are studied as possible solutions to enhance the compatibility between the inorganic fillers and polymer matrix. Morphology, thermomechanical and dielectric behavior of the prepared specim...

This paper describes the interaction between ubiquitin (UBI) and three sodium n-alkyl sulfates (SC(n)S) that have the same charge (Z = -1) but different hydrophobicity (n = 10, 12, or 14). Increasing the hydrophobicity of the n-alkyl sulfate resulted in (i) an increase in the number of distinct intermediates (that is, complexes of UBI and surfactant) that form along the pathway of unfolding, (i...

We report the analysis and characterization of natural and modified oligonucleotides by matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF MS). The present technology was highly improved for this class of compounds by using a new matrix, 2,4,6-trihydroxy acetophenone, together with di- and triammonium salts of organic or inorganic acids to suppress peak broa...

Organic-inorganic hybrid materials combine the advantages of both phases: hardness and strength inorganic phase elasticity toughness organic matrix. In present study, we have prepared nanocomposites with a poly(thiourethane) polymeric matrix silsesquioxane-type structures, thiols as reactive groups (POSS-A or POSS-B, synthesized in different pressure conditions), looking for covalent interactio...

A technique for the formation of gelatin thin films and composite coatings with silicon dioxide zinc oxide nanoparticles by spin coating has been developed. New data morphology structural characteristics formed nanocomposite were obtained atomic force microscopy. The dependences roughness parameters on content in polymer matrix are presented. It shown that introduction inorganic into structure ...

PSU/MMT nanocomposites are prepared by dispersing MMT nanolayers in a PSUmatrix via in situ photoinduced crosslinking polymerization. Intercalated methacrylate-functionalized MMT and polysulfone dimethacrylate macromonomer are synthesized independently by esterification. In situ photoinduced crosslinking of the intercalated monomer and the PSU macromonomer in the silicate layers leads to nanoco...

Matrices and sensors resulting from inorganic, organic and biological nanocomposites are presented in this overview. The term nanocomposite designates a solid combination of a matrix and of nanodimensional phases differing in properties from the matrix due to dissimilarities in structure and chemistry. The nanoocomposites chosen for a wide variety of health and environment sensors consist of An...