Using flushing solutions with different nonionic surfactants, this study investigated the remediation of polycyclic aromatic hydrocarbon (PAH)-contaminated soils with different organic carbon contents. Naphthalene and anthracene are the two delegates of PAHs used in the study. Contaminated soil packed in a stainless-steel column was continuously flushed with a surfactant solution at room temper...

The present study in the Firth of Forth, Scotland, emphasises the usefulness of biliary metabolite measurements in estuarine monitoring using the flounder (Platichthys flesus). The short time scale (a few hours) of response to polycyclic aromatic hydrocarbon (PAH) exposure, allowed clearer interpretation of trends and differences between sites. Such differences and trends in the metabolite data...

The study's objective is to evaluate the enhanced effect of Ghrelin (GRE) on sperm analysis and antioxidant system in male rats after inducing hyperthyroidism by L–thyroxin. (50 males) were split into five groups. first group consisted 10 that given normal saline for 30 days S.C set as a control group. While second (positive group) was with S.C, third at dose (0.5nmol/100μl saline) fourth (1nmo...

Soot-associated PAHs were exposed to simulated sunlight to investigate disappearance rates under environmental aging conditions and to examine the robustness of diagnostic ratios for PAH source apportionment. Naphthalene, acenaphthylene, acenaphthene, and fluorene showed an obvious two-phase disappearance in all experiments while phenanthrene and anthracene exhibited this behavior for all but t...

BACKGROUND Polycyclic aromatic hydrocarbons (PAHs) are known carcinogens and suspected endocrine disruptors. Prenatal exposure to PAHs has been associated with obesity in early childhood. OBJECTIVE We examined the association of urinary PAH metabolites with adiposity outcomes [body mass index (BMI) z-score, waist circumference (WC), and rate of obesity] in children and adolescents. METHODS ...

Polycyclic aromatic hydrocarbons (PAHs) typically contaminate the environment as complex assemblages of different chemical compounds. Modeling approaches provide a means of estimating the toxicity of these PAH mixtures. In the present study, we tested the hypothesis that the joint effects of four PAHs: pyrene, phenanthrene, fluoranthene and naphthalene, on the growth rate of the crustacean Daph...

Here, we present a surface-enhanced Raman spectroscopy (SERS) nanosensor for environmental pollutants detection. This study was conducted on three polycyclic aromatic hydrocarbons (PAHs): benzo[a]pyrene (BaP), fluoranthene (FL), and naphthalene (NAP). SERS substrates were chemically functionalized using 4-dodecyl benzenediazonium-tetrafluoroborate and SERS analyses were conducted to detect the ...

A modified cloning procedure was used to obtain large DNA insertions (20 to 30 kb) from Pseudomonas putida NCIB 9816 that expressed polycyclic aromatic hydrocarbon (PAH) transformation activity in Escherichia coli HB101. Four subclones (16 [in both orientations], 12, and 8.5 kb in size) were constructed from the initial clones. Naphthalene, fluorene, and phenanthrene transformations were invest...

This work presents the validation procedures of an analytical method to determine the 16 PAHs from the US EPA's priority pollutants list in sediment samples using ultrasonic extraction coupled to gas chromatography-mass spectrometry. The extraction techniques are altered by the construction of an extraction flask adapted to the ultrasonic bath that greatly reduces losses and increases extractio...

Naphthalene cations (C10H+8) were produced in a slit jet coupled with an electronic discharge, and cavity ring down was used to obtain its absorption spectrum in the region 645-680 nm. Two of the strongest C10H+8 bands previously characterized by matrix isolation spectroscopy were found, both with a fractional blue shift of about 0.5%. This is the first gas-phase electronic absorption spectrum ...