The limited fossil fuel prompts the prospecting of various unconventional energy sources to take over the traditional fossil fuel energy source. In this respect the use of hydrogen gas is an attractive alternate source. Attributed by its numerous advantages including those of environmentally clean, efficiency and renew ability, hydrogen gas is considered to be one of the most desired alternate....

Coal and biomass are abundant in supply but contain carbon which, to avoid greenhouse gas emissions, needs to be sequestered after the primary energy conversion. A comparison is reported here of the performance of four different coals and biomass in an iron oxide-based direct chemical looping combustion system. The principal aim is to identify the coal and biomass with the highest H2 to CO2 rat...

This project aims to develop new porous hydrogen storage materials which utilize molecular chemisorption of hydrogen rather than mere physisorption, and ultimately do this in low weight hybrid materials. Stronger binding of hydrogen should result in greater capacity and lower operating pressures at room temperature. These studies should lead to the design and synthesis of hydrogen storage mater...

In order to realize the promise of a hydrogen economy in this United States, it is essential to couple it with a simultaneous commitment to improve energy efficiency and increase the use of renewable energy. In this study, using detailed scenario analyses for the country as a whole and for urban areas, we found that a large-scale switch to hydrogen produced by a clean energy system would lead t...

Electricity demand varies daily, weekly, and seasonally. The cost and price of electricity to meet the peak demands can be an order of magnitude greater or more than the cost and price of electricity at times of minimum demand. Nuclear systems are capital intensive, with low operating costs relative to those for most other methods used to produce electricity; thus, nuclear energy is most compet...

Low-cost alkaline water electrolysis has been considered a sustainable approach to producing hydrogen using renewable energy inputs, but preventing hydrogen/oxygen mixing and efficiently using the instable renewable energy are challenging. Here, using nickel hydroxide as a redox mediator, we decouple the hydrogen and oxygen production in alkaline water electrolysis, which overcomes the gas-mixi...

  A theoretical density functional theory (DFT) study was performed on a series of the neutral N-phenylthiourea substituents (p-OC2H5, p-CH3, m-CH3, H, p-Cl, p-Br, m-Cl, and p-NO2) as the sensor of acetate and fluoride anions. The hydrogen bond character was analyzed as a scale ...