The implications of organically-modified silica-based materials in electrochemical science is reviewed along with some selected recent trends in the field of functionalized and sol–gel silica electrochemistry. These recent trends include the electro-assisted generation of organosilica films on solid electrode surfaces, the preparation and applications of sol–gel derived composite (carbon, gold,...

Several low-cost opportunities exist for scrubbing CO2 from waste gas streams, utilizing spontaneous chemical reactions in the presence of water and inexpensive or waste alkaline compounds. These reactions convert CO2 to bicarbonate or carbonate in dissolved or solid form, thus providing CO2 capture and low-risk CO2 storage underground, in the ocean, or in some cases on land. Useful by-products...

Chemical engineering operations commonly involve the use of packed and fluidized beds. These are devices in which a large surface area for contact between a liquid and a gas (absorption, distillation) or a solid and a gas or liquid (adsorption, catalysis) is obtained for achieving rapid mass and heat transfer, and particularly in the case of fluidized beds, catalytic chemical reactions. You wil...

The single crystals of the new isostructural compounds Sb3O4F and Y0.5Sb2.5O4F and the two previously known compounds M-SbOF and α-Sb3O2F5 were successfully grown by a hydrothermal technique at 230 °C. The new compound Sb3O4F crystallizes in the monoclinic space group P21/c; a = 5.6107(5) Å, b = 4.6847(5) Å, c = 20.2256(18) Å, β = 94.145(8)°, z = 4. The replacing part of Sb with Y means a sligh...

Icy dust grains in space act as catalytic surfaces onto which complex molecules form. These molecules are synthesized through exothermic reactions from precursor radicals and, mostly, hydrogen atom additions. Among the resulting products are species of biological relevance, such as hydroxylamine—NH2OH—a precursor molecule in the formation of amino acids. In this Letter, laboratory experiments a...

A theoretical two-phase-flow analysis is developed to describe the quasi-steady propagation, across a pressure jump, of a multi-phase deflagration in confined porous energetic materials. The difference, or overpressure, between the upstream (unburned) and downstream (burned) gas pressure leads to a more complex structure than that which is obtained for an unconfined deflagration in which the pr...

This paper presents a numerical investigation for laminar forced convection flow of a radiating gas in a rectangular duct with a solid element that makes a backward facing step. The fluid is treated as a gray, absorbing, emitting and scattering medium. The governing differential equations consisting the continuity, momentum and energy are solved numerically by the computational fluid dynamics t...

Our interest in the exchange reaction of oxygen between the gas phase and oxides is twofold: (i) to understand the mechanistic details of one of the "simplest" gas-solid reactions which nevertheless exhibits an astonishing complexity in terms of reaction pathways, (ii) to use this knowledge for improving electrochemical devices which rely critically on a fast oxygen incorporation rate such as c...

A polydimethylsiloxane-based microfluidic device allows monitoring local oxidation events in organic solvents at the level of an individual air bubble armored with surface-active low-surface energy catalytic particles. This new technique permits tunable design microreactors for gas-liquid-solid reactions.

The role of two oxygen sources, and water vapor, in the initiation KCl-induced high-temperature corrosion was addressed by studying high-alloyed commercial materials at 550 °C. differentiation between sources implemented with 18O-enriched 16O2. Based on results, solid-solid reaction KCl(s) protective oxide alloy surface appeared to be more responsible for than gas-solid KCl(g) oxide. Water invo...