Abstract Concrete is the most widely used construction material. It offers a desirable balance of cost, strength, moisture barrier qualities, and dimensional chemical stability. The rising costs aging infrastructure systems, however, point to need for further improvements in concrete properties. Carbon-based nanomaterials (CBNs) are predicted have excellent mechanical properties, so attractive ...

The elucidation of toxicity determinants of multi-walled carbon nanotubes (MWCNT) is still incomplete. Functionalization with carboxyl groups is, however, commonly used to mitigate MWCNT toxicity, although the rationale for the mitigating effect has not been fully clarified yet. In this work, two optimized chemical vapor deposition methods were employed to obtain MWCNT of comparable length but ...

In order to improve the dispersibility of multi-walled carbon nanotubes (MWCNT) in aqueous media, MWCNT were functionalized with tetrahydrofurfuryl polyethylene glycol (TFPEG) in a one-pot, fast and environmentally friendly method. To reduce defects and eliminate the acid-treatment stage, an electrophonic addition reaction under microwave irradiation was employed. Surface functionalization was ...

Chemically functionalized carbon nanotubes (f-CNTs) have been used in proof-of-concept studies to alleviate debilitating neurological conditions. Previous in vivo observations in brain tissue have suggested that microglia - acting as resident macrophages of the brain - play a critical role in the internalization of f-CNTs and their partial in situ biodegradation following a stereotactic adminis...

The strong affinity of carbon nanotubes (CNTs) to environmental contaminants has raised serious concern that CNTs may function as a carrier of environmental pollutants and lead to contamination in places where the environmental pollutants are not expected. However, this concern will not be realized until the contaminants are desorbed from CNTs. It is well recognized that the desorption of envir...

The frequency dependence of dielectric constant for composites polyaniline (PANI) and multi-walled carbon nanotube (MWCNT) with different degree functionalization is studied at low temperature (down to 4.2 K) magnetic field (up 3 T) applied both in parallel perpendicular direction ac electric field. A relaxation phenomenon observed all the MWCNT/PANI by applying directions, below 103 Hz. Howeve...

Alternating exposures of nitrogen dioxide gas and trimethylaluminum vapor are shown to functionalize the surfaces of single-walled carbon nanotubes with a self-limited monolayer. Functionalized nanotube surfaces are susceptible to atomic layer deposition of continuous, radially isotropic material. This allows for the creation of coaxial nanotube structures of multiple materials with precisely c...