A new method for the determination of trace copper(II) in food samples by Cloud Point Extraction(CPE) combined with Flame Atomic Absorption Spectrometry(FAAS) is presented and evaluated. The method is based on the fact that hydrophobic complex of copper(II) with sodium diethyldithiocarbamate (DDTC) was formed at pH 6.0 and subsequently the hydrophobic complex was extracted into surfactant-rich ...

Flame atomic absorption spectrometry (FAAS) was adopted to detect the construction vehicles automatic transmission through simultaneous determination of typical metal elements contents (Copper, Chromium and Iron) in automatic transmission fluid (ATF). Standard curves of Copper, Chromium and Iron were portrayed. Six parallel tests were implemented and the relative standard deviations (RSD) were ...

This paper reports the preparation of a phosphorylated cotton chelator (PCC) by solid phase esterification of phosphoric acid (PA) onto defatted cotton fibres using urea as the catalyst. The synthesized PCC was employed for the preconcentration of copper from water samples prior to its determination by flame atomic absorption spectrometry (FAAS). The preconcentration of copper was studied under...

Ground fish scales were characterized as a solid phase extraction medium for preconcentration of parts per billion levels of transition elements prior to their flame atomic absorption spectroscopic (FAAS) determination. At the indicated optimum pH, sorption follows the order Cd (pH 7.0) ≥ Pb (pH 5.5)> Fe (pH 4.8) > Cu > Zn (pH 6.0) > Ni (pH 7.5) > Mn (pH 8.5) > Cr (pH 4.8). At pH 5.5, following...

Human hair shavings were characterized as a sorbent for trace metals. At pH 7.0 metal sorption follows the order Pb(II)>Cd(II)>Cr(VI)>Fe(III)>Cu(II)>Ni(II)>Mn(VI). Metal recovery is quantitative for Pb and Cd after 30 min of equilibration. Recovery of other metals is less quantitative and varies with pH. For example, while Cu is best recovered at pH 5, Ni and Mn are sorbed optimally in the basi...

dispersive liquid-liquid microextraction technique based on solidification of a floating organic drop (dllme-sfo) combined with flame atomic absorption spectrometry was developed for determination of thallium in water sample. an appropriate mixture of acetone and 1-undecanol was rapidly injected into an aqueous sample containing tlcl4- which forms an ion pair with brilliant green reagent and as...

a study of the atmospheric particulate size distribution of total suspended particulate matter(tspm) and associated heavy metals concentrations has been carried out for the urban part of sarajevo city,bosnia and herzegovina. urban particles (n=150) were collected using a high volume air sampler equippedwith a 6-stage impactor. apart from fe which has been determined by flame atomic absorption s...

This research aimed to quantify the speciation of chromium in different industrial effluent samples Hyderabad and Jamshoro, Pakistan. The hexavalent (Cr(VI)) was determined by microsample injection system flame atomic absorption spectroscopy (MIS-FAAS). total measured MIS-FAAS after oxidation trivalent (Cr(III)) Ce(SO4)2 an acidic medium (0.07 M H2SO4). content Cr(III) difference method (total ...

a simple, highly sensitive, accurate and selective method was presented for determination of trace amounts of cu (ii) in water samples. the stability of an n, n´ -disalicylideneethylenediamine modified nano geraphene especially in concentrated hydrochloric acid was studied which used as a recycling and pre-concentration reagent for further uses of n, n´-disalicylideneethylenediamine modified na...