نتایج جستجو برای: ferrocene
تعداد نتایج: 1909 فیلتر نتایج به سال:
Graphene nanoplatelets (GNPs) are 'tagged' with 1-(biphen-4-yl)ferrocene. Chronoamperometry is then utilised to observe single particle impacts when GNPs suspended in solution collide with a carbon fibre micro wire electrode held at an oxidising potential, resulting in current/time transient "spikes". The impacts are associated with two types of charge transfer: Faradaic due to oxidation of the...
Confining lithium polysulfide intermediates is one of the most effective ways to alleviate the capacity fade of sulfur-cathode materials in lithium-sulfur (Li-S) batteries. To develop long-cycle Li-S batteries, there is an urgent need for material structures with effective polysulfide binding capability and well-defined surface sites; thereby improving cycling stability and allowing study of mo...
An electrochemical response of glucose and lactate biosensors which were prepared by coating a platinum electrode with a thin film composed of concanavalin A and mannose-labeled glucose oxidase (GOx) or lactate oxidase (LOx) was evaluated in the presence of ferrocene derivatives as electron mediator. Both glucose and lactate biosensors showed catalytic current to glucose and lactate, respective...
The ferrocene-benzobisimidazole derivative shows high affinity for Pb(2+) and Zn(2+) metal cations over a range of other metal cations examined. In the presence of Pb(2+) the emission spectrum is red-shifted by 13 nm with an important chelation-enhanced fluorescence effect (CHEF) CHEF = 55. The presence of Zn(2+) cations also induced a perturbation of the emission spectrum although to a lesser ...
In this paper, we report a novel surface-tethered DNA nanodevice that may present three states and undergo conformational changes under the operation of pH. Besides, convenient regulation on the electrode surface renders the construction and operation of this DNA nanodevice restorable. To make full use of this DNA nanodevice, ferrocene (Fc) has been further employed for the fabrication of the m...
A new donor-acceptor dyad (7) involving a ferrocene moiety as donor and an azafullerene as acceptor has been synthesized by treating bisazafullerenyl (1) with ferrocenium hexafluorophosphate. This compound represents the first example of a fullerene-based dyad where two electroactive groups are connected by only a single sigma-bond. The cyclic voltammetry of 7, in comparison to the correspondin...
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