Many potential pitfalls and artefacts have been described in PET imaging that uses F-18 fluorodeoxyglucose (FDG). Normal uptake of FDG occurs in many sites of the body and may cause confusion in interpretation particularly in oncology imaging. Clinical correlation, awareness of the areas of normal uptake of FDG in the body and knowledge of variation in uptake as well as benign processes that ar...

The methylthiotransferases (MTTases) represent a subfamily of the S-adenosylmethionine (AdoMet) radical superfamily of enzymes that catalyze the attachment of a methylthioether (-SCH3) moiety on unactivated carbon centers. These enzymes contain two [4Fe-4S] clusters, one of which participates in the reductive fragmentation of AdoMet to generate a 5'-deoxyadenosyl 5'-radical and the other of whi...

The microstructures of eutectics between compounds were studied for systems MnO-MnS, NaCl-NaF, NaBr-NaF, LiF-NaF, and FeO-FeS. With the exception of FeS, all the compounds had the NaC1-type structure. In the systems having only NaC1-type structures, the lamellas of the two eutectic phases had matching crystal orientations. There was less consistency among the eutectic systems, however, than bet...

The first all-alkaline-earth beryllium borate with fluorine anions, Ca3Be6B5O16F, was synthesized by a spontaneous crystallization flux method using LiF-B2O3 as the flux. The structural framework of Ca3Be6B5O16F is composed of the inter-connected [Be6B3O16] and [BO3] fundamental building blocks, with [CaO7F] distorted polyhedra located in the interstitial sites. The [Be6B3O16] group is discover...

Layered transition-metal chalcogenides have emerged as a fascinating new class of materials for catalysis. Here, we present periodic density functional theory (DFT) calculations of the adsorption of thiophene and the direct desulfurization reaction pathways on the (001), (011), and (111) surfaces of layered FeS. The fundamental aspects of the thiophene adsorption, including the initial adsorpti...

Pressure is a powerful tool to study iron-based superconductors. Here, we report systematic high-pressure transport and structural characterizations of the newly discovered superconductor FeS. It is found that superconductor FeS (tetragonal) partly transforms to a hexagonal structure at 0.4 GPa, and then completely transforms to an orthorhombic phase at 7.4 GPa and finally to a monoclinic phase...