The water sensing properties of two efficient two-component fluorescent "turn-on" chemo-sensors based on the 7-dialkylaminocoumarin oxime acid-base equilibrium were investigated. Interestingly, although simple frontier orbital analysis predicts an intramolecular photoinduced electron transfer quenching pathway in conjugated oximates, TD-DFT (Time-dependent density functional theory) quantum che...

The optical properties (absorption and fluorescence) of fluorescein sodium were investigated with changing the bulk pH value in aqueous, water-methanol mixed and dodecylammonium propionate reversed micellar solutions. A strong buffer action was found in the reversed micellar solutions. The pK a values for the equilibrium between fluorescein monoand di-anions in the ground and excited singlet st...

Background: A dressing often covers the wound to accelerate its healing. Hydrocolloid-type dressing to give better conditions for healing has been developed consisting of gelatin, pectin, water and hydrophilic polymer which promote healing. In recent years, much attention has been focused on the research and development of polymer hydrogels as biomaterials, such as contact lenses, wound dressin...

adsorption and water treatment of ca (ii) and mg (ii) hardness were investigated via adsorption of metal ions onto commercial polyacrylic acid hydrogel beads as a novel sorbent for metal ions (ca2+, mg2+) removal and water treatment. batch equilibrium technique was carried out under the influence of solution ph, contact time, sorbent dosage, initial metal concentration and competitive study. th...

HAPEX-MOBILHY data, consisting of one year of hourly atmospheric forcing data at Caumont (SAMER No. 3, 43.68°N, 0.1°W) were used repeatedly to run the two-layer Variable Infiltration Capacity (VIC-2L) land-surface scheme until the model reached equilibrium in its water and energy balance. The equilibrium results are compared with one year of weekly soil moisture measurements at different depths...

Taking advantage of its unusual fluorescent properties, the incorporation of B-phycoerythrin (B-PE) in aerosol OT (AOT, sodium bis-(2-ethylhexyl) sulphosuccinate)/water/isooctane microemulsions was investigated by following their steady-state and time-resolved fluorescence as a function of the water-to-surfactant molar ratio, w(0). The fluorescent intensity at 575 nm increased continuously with...

Abstract: Hydrogen production via Sorption-Enhanced Chemical-Looping reforming combines hydrocarbons reforming (in this case methane reforming), by chemical-looping auto-thermal reforming, with water-gas shift and carbonation reactions. Both H2 production rate and concentration depend on the chemical equilibrium that is established in the fuel reactor and that is influenced by several parameter...

Water permeation through nanometric channels, generally a coupled many-body process, is described in this study by a single collective coordinate. A collective diffusion model is proposed in which water movement at equilibrium is characterized as an unbiased diffusion along this coordinate and water transport in the presence of a chemical potential difference is described as one-dimensional dif...

Abstract Dynamic water vapor sorption experiments were carried out using beech wood dust (from untreated and thermally modified wood) of two-particle sizes, (< 25 80–250 µm), obtained from abrasive sanding. Sorption isotherms parameterized with the GAB GDW models. Dust had significantly lower equilibrium moisture content compared to material, due reduction in primary sites treated material. ...