The nitration of Phenothiazine (PHEN) in acetonitrile (ACN) in the presence of excess NaNO2 has been studied in detail. First, the electrochemical behavior of the reactants was investigated by cyclic voltammetry to determine the electrolysis conditions. Controlledpotential electrolysis was used for the electrosynthesis. Introduction Although the nitration of organic compounds is an area in expa...

It was hypothesized that a lack of acetogenic biomass (biocatalyst) at the cathode of a microbial electrosynthesis system, due to electron and nutrient limitations, has prevented further improvement in acetate productivity and efficiency. In order to increase the biomass at the cathode and thereby performance, a bioelectrochemical system with this acetogenic community was operated under galvano...

A transition-metal-free direct electrolytic C?H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by situ electrolyte. novel, efficient intramolecular intermolecular demonstrated using a simple reaction setup.

Microbial electrosynthesis of multi-carbon organic compounds is a promising novel technology for converting electricity into renewable organic molecules as well as for storing electrical energy. This project explored the breath of possible platform organisms to be used in this emerging technology and identified the potential as well as the limitations. Of the multiple microorganism and experime...

The electrosynthesis of H 2 O via a two-electron pathway oxygen reduction reaction (2e ? ORR) has emerged as promising way carbon-free and on-site production . Active selective electrocatalysts for the 2e ORR are essential achieving high -to-H conversion efficiency. In this review, we present recent progress in development including Pt-group-metal (PGM) non-PGM atomically dispersed catalysts me...