the dye-sensitized solar cells (dssc) have been regarded as one of the most promising new generation solar cells. tremendous research efforts have been invested to improve the efficiency of solar energy conversion which is generally determined by the light harvesting efficiency, electron injection efficiency and undesirable electron lifetime. in this review, various characteristics of dye-sensi...

4-4'-Disubstituted biphenyl boronic acids (BBAs) are push-pull fluorophores with "turn-on" fluorescence properties. Upon carbohydrate triol binding, BBA boronate esters can participate in photon-induced electron transfer, giving a twisted intramolecular charge transfer (TICT) complex. The resulting TICT emissions distinguish between carbohydrates that bind to boron as a diol versus triol unit, ...

Capping agents, key for nanoparticle stability, may hugely influence chemical behaviour. We show that differently capped gold nanoparticles, with either citrate or cetyl trimethylammonium bromide (CTAB) capping agents, show qualitatively different electron transfer properties. Specifically through cyclic voltammetry and nanoimpact studies the CTAB promoted dissolution of gold nanoparticles is s...

Functional quantum dot (QD)-based nanostructures are often constructed through the self-assembly of QDs with binding partners (molecules or other nanoparticles), a process that leads to a statistical distribution of the number of binding partners. Using single QD fluorescence spectroscopy, we probe this distribution and its effect on the function (electron-transfer dynamics) in QD-C60 complexes...

The electron transfer properties of proteins are normally measured as molecularly averaged ensembles. Through these and related measurements, proteins are widely regarded as macroscopically insulating materials. Using scanning tunnelling microscopy (STM), we present new measurements of the conductance through single-molecules of the electron transfer protein cytochrome b(562) in its native conf...

in this research, al-ni particle composite strips are formed by accumulative roll bonding (arb) process using al strips and ni powder. the rule of arb cycles and volume percentage (vol%) of ni powder on the microstructure, wear resistance and mechanical properties of the formed composites are investigated. according to the tensile test results, the yield stress and tensile strengths of the al -...

It has long been known that in acid solution phenazine and related compounds, including N-alkylated derivatives, are oxidized and reduced in distinct l-electron steps, thereby passing through a semiquinoid intermediate (l-4). These semiquinoid forms are stable in acid and have a characteristic green color which readily distinguishes them from the fully oxidized or fully reduced compounds. N-Met...

Glassy carbon (GC) surfaces modified with monolayers of biphenyl and nitrobiphenyl molecules were examined as voltammetric electrodes for ferrocene, benzoquinone, and tetracyanoquinodimethane electrochemistry in acetonitrile. The modified electrodes exhibited slower electron transfer than unmodified GC, by factors that varied with the monolayer and redox system. However, after a negative potent...

We attempt to detect the possibility to modify the catalytic property of Pt/graphene using small organic molecule. Results of density functional theory calculations show that ssDNA segment and L-leucine modify the electron transfer at the interface, changing the electronic property and redox property of Pt/graphene catalyst system. L-leucine promotes electron transfer from Pt and increases the ...