The process of desorption for the system of O,/Pd( 111) under excitation by 100 fs pulses of visible light has been examined. Molecular desorption is found to occur with high efficiency and a nonlinear dependence on laser fluence. Direct time-domain measurements using a two-pulse correlation scheme reveal a dominant subpicosecond response together with a weaker, but significant correlation pers...

We report studies of photon-stimulated desorption, also known as light-induced atomic desorption, of sodium atoms from a vacuum-cell glass surface used for loading a magneto-optical trap (MOT). Fluorescence detection was used to record the trapped atom number and the desorption rate. We observed a steep wavelength dependence of the desorption process above 2.6 eV photon energy, a result signifi...

Introduction X-ray standing waves (XSW) using electrons and fluorescence photons as secondary signals has become a standard technique to determine adsorbate structures. However, when a sample is irradiated by intense light, desorption of ions is also a frequently observed phenomenon which is known as photon-stimulated desorption (PSD). But, this signal is of a fundamentally different physical n...

An in situ thermal desorption study of solvated aluminum hydride (alane) by transmission electron microscopy and selected area diffraction has permitted characterisation of the structural and morphological changes during desorption of solvent and hydrogen in real-time; this powerful technique for studying hydrogen storage materials complements several others already employed.

There are numerous indications that adsorbed particles on a surface do not desorb statistically, but that their spatial distribution is important. Evidence almost exclusively comes from temperature-programmed desorption, the standard method for measuring desorption rates. However, this method, as a kinetics experiment, cannot uniquely prove an atomic mechanism. Here we report a low-energy elect...

we evaluated the effect of fe/alumina catalyst contained different cadmium contents and two synthesis temperatures on producing carbon nanotubes by chemical vapor deposition of methane as a feedstock.  x-ray powder diffraction (xrd), n2 adsorption-desorption, scanning electron microscopy (sem), transmission electron microscopy (tem), raman spectroscopy and thermogravimetry analysis (tga) were u...

This paper presents a systematic study of the surface chemistry, porous texture and adsorptive characteristics of prepared new activated carbon using Persian mesquite grain. Several techniques and methodologies such as, proximate analysis, N2 adsorption–desorption isotherms, scanning electron microscope (SEM), Fourier transform infrared spectroscopy(FT-IR), X-ray Diffraction (XRD), X-ray photoe...

Background: Focused electron beam induced deposition (FEBID) allows for the deposition of free standing material within nanometre sizes. The improvement of the technique needs a combination of new precursors and optimized irradiation strategies to achieve a controlled fragmentation of the precursor for leaving deposited material of desired composition. Here a new class of copper precursors is s...

An increasing number of studies have recently reported the rapid degradation of hybrid and all-inorganic lead halide perovskite nanocrystals under electron beam irradiation in the transmission electron microscope, with the formation of nanometer size, high contrast particles. The nature of these nanoparticles and the involved transformations in the perovskite nanocrystals are still a matter of ...

Gas desorption from field emitter array (FEA) cathode and phosphor screen anode in a flat panel display during lifetime operation can affect cathode electron emission and degrade display performance and uniformity. We have measured the outgassing products from selected FEA-phosphor pairs in an ultrahigh vacuum system equipped with a calibrated quadrople residual gas analyzer. Different low volt...