A disk pressed from commercial SnO2 powder, sandwiched between two nickel screen current collectors, was used as a lithium-ion secondary anode. Its electrochemical lithium insertion–extraction behavior was investigated by galvanostatic charge–discharge and galvanostatic intermittent titration (GITT) using a microcurrent on one current collector. The transelectrode voltage was measured to monito...

In this study the effect of crystallite size reduction and microstructure on the electrochemical corrosion behavior of nanocrystalline nickel (NC Ni) were investigated using Tafel polarization and electrochemical impedance spectroscopy (EIS) measurements in 10 wt.% NaOH. NC Ni coatings were produced by direct current electrodeposition using chloride baths in presence and absence of saccharin as...

Composite electrodes of polyaniline/MnO2-Multi walled carbon nanotube (PANI/MnO2-MWCNT), MnO2-MWCNT nanocomposites and MWCNT was produced by the in situ direct coating approach. The supercapacitor performance of the nanocomposites was studied by Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). The electrochemical properties of electrodes were also investig...

In this investigation, attempts were directed to study the inhibitive effects of nitrite and phosphate base inhibitors for the carbon steel alloy samples, which are used in an acid gas treatment process (The SULFIRAN® solution), in Fe-EDTA solution. Electrochemical techniques, i.e. polarization curves and electrochemical impedance spectroscopy (EIS), were used to evaluate the inhibition efficie...

Electrochemical impedance spectroscopy is a crucial tool for the detection and study of various biological substances, from DNA and proteins to viruses and bacteria. It does not require any labelling species, and methods based on it have been developed to study cellular processes (such as cell spreading, adhesion, invasion, toxicology and mobility). However, data have so far lacked spatial info...

We present an integrated label-free biosensor based on surface plasmon resonance (SPR) and Faradaic electrochemical impedance spectroscopy (f-EIS) sensing modalities, for the simultaneous detection of biological analytes. Analyte detection is based on the angular spectroscopy of surface plasmon resonance and the extraction of charge transfer resistance values from reduction-oxidation reactions ...

This work proposes a new time-domain integration method to realize Electrochemical Impedance Spectroscopy (EIS). Unlike traditional EIS systems which use a quadrature sinusoid stimulus, we propose a low-frequency, lowamplitude sinusoid stimulus, which is realized through a sinusoid DAC without the need for analog filter. The error caused by harmonic generation can be suppressed through integrat...

Sulfoanted poly(ether ether ketone) membranes were prepared by the sulfonating agent sulfuric acid. These membranes were modifed by incorporating conducting polymer polypyrrole in order to increase the ionic conductivity and reduce the methanol transmission rate. The modifed composite membranes were then compared on the basis of ionic conductivity, methanol transmission...

Local electrochemical impedance spectroscopy (LEIS), which provides a powerful tool for exploration of electrode heterogeneity, has its roots in the development of electrochemical techniques employing scanning of microelectrodes. The historical development of local impedance spectroscopy measurements is reviewed, and guidelines are presented for implementation of LEIS. The factors which control...