The study reports some preliminary investigations on the template free synthesis of a scantly investigated polyaniline (PANI) derivative-Phenylenediamine (PDA) by template free method in the presence of Oxalic acid (OA) (dopant), using Ammonium Persulfate as oxidant. Polymerization of Phenylenediamine (PDA) was confirmed by the FT-IR as well as UV–visible studies. The morphology of Phenylenedia...

The efficiencies of charge exchange reaction in dopant-assisted atmospheric pressure chemical ionization (DA-APCI) and dopant-assisted atmospheric pressure photoionization (DA-APPI) mass spectrometry (MS) were compared by flow injection analysis. Fourteen individual compounds and a commercial mixture of 16 polycyclic aromatic hydrocarbons were chosen as model analytes to cover a wide range of p...

The study reports some preliminary investigations on the template free synthesis of a scantly investigated polyaniline (PANI) derivative-Phenylenediamine (PDA) by template free method in the presence of Oxalic acid (OA) (dopant), using Ammonium Persulfate as oxidant. Polymerization of Phenylenediamine (PDA) was confirmed by the FT-IR as well as UV–visible studies. The morphology of Phenylenedia...

Oxides with the cubic fluorite structure, e.g., ceria (CeO2), are known to be good solid electrolytes when they are doped with cations of lower valence than the host cations. The high ionic conductivity of doped ceria makes it an attractive electrolyte for solid oxide fuel cells, whose prospects as an environmentally friendly power source are very promising. In these electrolytes, the current i...

Throughout the past decades, doped-ZnO has been widely used in various optical, electrical, magnetic, and energy devices. While almost every element in the Periodic Table was doped in ZnO, the systematic computational study is still limited to a small number of dopants, which may hinder a firm understanding of experimental observations. In this report, we systematically calculate the single-ele...

Changes in birefringence and dichroism induced by light were monitored after pulse excitation of a nematic phase consisting of a mixture of a low molecular weight liquid crystal (ZLI-1132) and a dopant 4-(N,N-dimethylamino)-azobenzene. After excitation in the UV, large changes in the light transmitted by the sample, placed between polarizers at various angles or in the polarized absorption spec...

Alkaline-earth metallic dopant can improve the performance of anatase TiO2 in photocatalysis and solar cells. Aiming to understand doping mechanisms, the dopant formation energies, electronic structures, and optical properties for Be, Mg, Ca, Sr, and Ba doped anatase TiO2 are investigated by using density functional theory calculations with the HSE06 and PBE functionals. By combining our result...

The unique capability of secondary electrospray ionization (SESI) as a nonradioactive ionization source to detect analytes in both liquid and gaseous samples was evaluated using aqueous solutions of three common military explosives: cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX), nitroglycerin (NG) and pentaerythritol tetranitrate (PETN). The adducts formed between the compounds and their re...

In this paper, we present an enhanced Differential Hall Effect method (DHE) for Si and SiGe ultrathin layers for the investigation of dopant activation in the surface region with sub-nanometre resolution. In the case of SiGe case, which constitutes the most challenging process, we show the reliability of the SC1 chemical solution (NH4OH:H2O2:H2O) thanks to its slow etch rate, stoichiometry cons...

Proton uptake in undoped and Y-doped BaPrO3 has been measured by cold neutron prompt-gamma activation analysis, and compared to the proton uptake in Gd-doped BaCeO3, as determined by the same technique. The conventional proton incorporation model of perovskites in which oxygen ion vacancies, generated by the introduction of the trivalent dopant onto the tetravalent perovskite site, are filled w...