This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...

This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...

in the present work, the electrooxidation of formic acid and formaldehyde; potentially important fuels for future fuel cells, was investigated on the fe3o4@pt core-shell nanoparticles/carbon-ceramic electrode (fe3o4@pt/cce). the fe3o4@pt nanoparticles were prepared via a simple and fast chemical method and their surface morphology, nanostructure properties, chemical composition, crystal phase, ...

A new voltammetric sensor for determination of uric acid (UA) by Cuppercomplex- multiwalled carbon nanotube (Cu-complex-CNT) nanocomposite modifiedcarbon paste electrode (CPE) is reported. The electrocatalytic behavior of theCu-complex-CNT nanocomposite modified CPE was studied in pH 2.0 phosphatebuffer solution by chronoamperometry (CA) and cyclic voltammetry (CV) in th...

In this research, Ag/ZnO nanocomposites were prepared and characterized by transition electron microscopy (TEM), the energy dispersive X-ray spectrum (EDS) and X-ray diffraction patterns (XRD). These nanocomposites were used as catalysts for the oxidation of toluene to benzaldehyde and benzoic acid with hydrogen peroxide (H2O2) and tert-butylhydroperoxide (TBHP) as oxidizing agent in the liquid...

in this study, undoped zno and doped with fe and mn nanostructures were synthesized by hydrothermal method. the morphology of nanostructures was characterized by scanning electron microscope. the electrochemical response of the carbon paste electrode modified with nanoparticles of zno and also zno doped with fe and mn toward levodopa (l-dopa) was studied. studies of cyclic voltammetry using pro...

This paper is consisted in the synthesis of platinum-based electrocatalysts supported on carbon (Vulcan XC-72) and investigation of the addition of gallium in their physicochemical and electrochemical properties toward ethanol oxidation reaction (EOR). PtGa/C electrocatalysts were prepared through thermal decomposition of polymeric precursor method at a temperature of 350°C. Six different compo...

this study describes a new simple, sensitive and selective catalytic kinetic spectrophotometricmethod for the determination of vanadium (v). the method is based upon the catalytic effect ofvanadium (v) on the oxidation of carminic acid by bromate in sulfuric acid media. the reaction wasfollowed spectrophotometrically by measuring the decrease in absorbance at 490 nm and thedependence of sensiti...

Hydrazine has been identified as a carcinogenic mutagenic, hepatotoxic, and neurotoxin material. A metal-organic framework with tetragonal symmetry, DMOF-1 (Zn2(bdc)2dabco) was synthesized by a versatile and facile technique, followed by its efficient development and validation as hydrazine electrochemical sensor. Differential pulse voltammetry (DPV), linear sweep voltammetry (LSV), and c...

The catalytic oxidation of toluene to benzoic acid in the liquid phase has been studied in an un-stirred tank reactor. Low concentration of acetic acid was added in order to increase the solubility of the catalyst in toluene. The dependence of the rate of reaction on the concentration of toluene catalyst and oxygen pressure was studied. It has been suggested that liquid phase oxidation of t...