The reaction of hydrogen peroxide with 5, 10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato- iron(III) hydrate [(P)FeIII(H2O)] has been investigated in water between pH 1 and pH 12. The water-soluble (P)FeIII(H2O) neither aggregates nor forms a mu-oxo dimer. The pH dependence and rate-limiting second-order rate constants (kly) for oxygen transfer from H2O2 and HO2- to the iron(III) po...

The syntheses, structures and magnetic properties of the coordination compounds of formula [FeIII(acac2-trien)][MnIICrIII(Cl2 An)3]·(CH3CN)2 (1), [FeIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (2) and [GaIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (3) are reported. They exhibit a 2D anionic network formed by Mn(ii) and Cr(iii) ions linked through anilate ligands, while the [FeIII(acac2-trie...

Abstract. Iron(III) carboxylate photochemistry plays an important role in aerosol aging, especially the lower troposphere. These complexes can absorb light over a broad wavelength range, inducing reduction of iron(III) and oxidation ligands. In presence O2, ensuing radical chemistry leads to further decarboxylation, production .OH, HO2., peroxides, oxygenated volatile organic compounds, contrib...

The π-conjugated tetrathiafulvalene (TTF) annulated ligand was introduced into a dicyanometallate for the first time, leading to the synthesis of the versatile redox-active dicyanideferrite building block [(n-Bu)4N][Fe(TTFbp)(CN)2] (H2TTFbp = N-(2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-5-(picolinamido) benzo[d][1,3]dithiol-6-yl) picol inamide). The incorporation of the new precursor with c...

New molecular complexes of fullerenes C60 and C70 with tetraphenylporphyrins [M(tpp)] in which M-H2, MnII, CoII, CuII, ZnII and Fe(III)Cl, have been synthesised. Crystal structures of two C60 complexes with H2TPP, which differ only in the number of benzene solvated molecules, and C60 and C70 complexes with [Cu(tpp)] have been studied. The fullerene molecules form a honeycomb motif in H2TPP.2C60...

The title compound, [Cu2(ClO4)(C14H13N2O)2(H2O)]ClO4, crystallizes as an unsymmetrical dinuclear cation bridged by the phen-oxy O atoms with one CuII atom coordinated by a water mol-ecule and the other by a perchlorate anion, thus making both CuII atoms five-coordinate, and with a further perchlorate anion present for charge balance. A long inter-action [2.9893 (5) Å] between one of the two CuI...

Fabrication and electrochemical characteristics of the meso-2,3-dimercaptosuccinic acid (DMSA) self-assembled monolayer modified gold electrode were described. The modified electrode exhibited increased sensitivity and selectivity for CuII compared to the bare gold electrode by stripping voltammetry and the peak current was proportional to the concentration of CuII in the range of 8.0 10–7 1.2 ...

In the title complex, [Ca2Cu(C9H3O6)2(H2O)2] n , the CaII and CuII cations are bridged by the benzene-1,3,5-tri-carboxyl-ate anions (BTC3-) to form the coordination polymer, in which each BTC3- anion bridges two CuII and five CaII cations with a μ7 coordination mode. The CuII cation, located at an inversion centre, is in a nearly square-planar geometry defined by four O atoms from four bridging...

Using N2O4 donor symmetric ligand H2L and dca co-ligand, two new isostructural dinuclear CuII–LnIII complexes [Cu(Cl)(L)Ln(NO3)(CH3OH)(H2O)(dca)] [Ln=Ho (1CuHo), Gd (2CuGd)] [H2L = 6,6′-((1E,1′E)-(ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol); dca=dicyanamide] were designed, synthesized studied. In the compounds, geometric environment around nine-coordinated Ln(I...

A conducting molecular crystal TPP[MnIII(Pc)(CN)2]2 (MnIII: d4, S = 1, TPP = tetraphenylphosphonium and Pc = phthalocyanine) was fabricated. In its crystal structure, the [MnIII(Pc)(CN)2] units formed a one-dimensional regular chain along the c-axis with an overlap integral value of 8.6 × 10-3. TPP[MnIII(Pc)(CN)2]2 showed a semiconducting behaviour that also has been observed for isostructural ...