Present paper deals with the synthesis, spectral characterization and X-ray diffraction study of Zn(II) complex with Pioglitazone a new oral antidiabetic drug. The conductometric titration using monovariation method indicate that complex is ionic and L2M type which was further confirmed by Job’s method of continuous variation as modified by Turner and Anderson. Analytical data agree with the mo...

The interactions between an anionic dye, Acid Green 25 AG and the two cationic surfactants tetradecyltrimethylammonium bromide TTAB, and hexadecyltrimethylammonium bromide CTAB in aqueous solutions far below the CMC are studied using the conductometric method at different temperature. The equilibrium constants and other thermodynamic functions for the process of dye-surfactant ion pair formatio...

The complexation reaction between iodine and 1,10-Diaza-18-Crown-6 (DA18C6) has been studied in acetonitrile by spectrophotometric, biamperometric and conductometric techniques. The results are indicative of the formation of [(CH3CH)nI+.I¯3] from iodine and acetonitrile, and the formation of DA18C6 I+. I¯ from DA18C6 and [(CH...

We introduce a new method to modify films of nanofibrillated cellulose (NFC) to produce non-porous, water-resistant substrates for diagnostics. First, water resistant NFC films were prepared from mechanically disintegrated NFC hydrogel, and then their surfaces were carboxylated via TEMPO-mediated oxidation. Next, the topologically functionalized film was activated via EDS/NHS chemistry, and its...

Polymerization of β-phenyl glutaconic diethyl ester (GE) with various diamines (DA) at 1:2 molar ratios in 1,4dioxane solvent was carried out at reflux temperature. The resultant amino terminated unsaturated oligomers (ATUP) were characterized by elemental analysis, number of terminal amino groups, IR spectral studies, number average molecular weight estimated by non-aqueous conductometric titr...

Ionization processes in aqueous solutions have long been a point of central interest to physical chemistry. Much progress has been made in recent years in understanding the charging properties of such different entities as small molecules, polyelectrolytes and various kinds of interfaces [1]. In this context, silica and silicate glass surfaces immersed in water are known to acquire a negative s...

Cationic amphiphilic diblock copolymers containing quaternized poly (2vinylpyridine) chain as a hydrophilic segment (PIp-b-PNMe2VP) were synthesized by living anionic polymerization. By IR measurement, we confirmed the quaternization of the polymer (PIp-b-PNMe2VP), and determined the degree of quaternization by conductometric titration. The surface tension experiment showed that the polymers ar...