In this study, we describe the growth of carbon nanotubes on commercial iron nanoparticles without carbon shell (Fe (nm), size 2O3 and Fe* (nm)/MgO) was carried out by mixing commercial Fe* nanoparticles (as catalyst) with Al2O3 and MgO powders (as supports)by using ball-milling method. The results show in spite of the fact that ball-milling process can have neg...

A series of modified solid polymethylaluminoxane (sMAO) catalyst supports have been developed for slurry phase ethylene polymerisation, using aryl di-ol modifier groups.

There is a widespread interest in developing methods to recover homogeneous catalysts, particularly chiral catalysts, from a reaction mixture. The impetus to recover and reuse homogeneous catalysts stems not only from an economic standpoint but also from the need to eliminate contamination of the transition metal catalyst in the product and in the waste streams. The challenge is to recover the ...

Conventional supported metal catalysts are metal nanoparticles deposited on high surface area oxide supports with a poorly defined metal-support interface. Typically, the traditionally prepared Pt/ceria catalyzes both methanation (H2/CO to CH4) and water-gas shift (CO/H2O to CO2/H2) reactions. By using simple nanochemistry techniques, we show for the first time that Pt or PtAu metal can be crea...

Aqueous phase reforming (APR) of biomass derived feedstock producing hydrogen was reviewed. The APR process was discussed based on different feedstock categories such as sugars, polyols and ethanol. The mechanism of APR was analyzed referring to different structures of feedstock. The reaction pathways of APR were investigated. The usage of catalysts should be judged by feedstock on the requirem...

Graphitic carbon nitrides are investigated for developing highly durable Pt electrocatalyst supports for polymer electrolyte fuel cells (PEFCs). Three different graphitic carbon nitride materials were synthesized with the aim to address the effect of crystallinity, porosity, and composition on the catalyst support properties: polymeric carbon nitride (gCNM), poly(triazine) imide carbon nitride ...

The bio-based substrate and target product 2,5-bishydroxymethylfuran (BHMF) demonstrated to influence the reaction kinetics in the homogeneous reduction of 5-hydroxymethylfurfural (HMF) catalyzed by the Ru-based Shvo's catalyst. A combined experimental and computational study supports an important role of the -CH2OH moiety which may be involved in the catalytic cycle toward the formation of dif...

Catalyst supports are known to play important role in governing overall catalyst activity and durability. Here, a new type of SnO2eTiO2 solid solution (TixSn1-xO2) support was prepared via a solvothermal method with substitution of Ti4þ by Sn4þ in the TiO2 lattice. Furthermore, the TixSn1-xO2 was combined with conventional carbon black (Vulcan XC-72) to prepare a hybrid support (TixSn1-xO2eC) f...

Creating highly active and stable metal catalysts is a persistent goal in the field of heterogeneous catalysis. However, a real catalyst can rarely achieve both of these qualities simultaneously due to limitations in the design of the active site and support. One method to circumvent this problem is to fabricate firmly attached metal species onto the voids of a mesoporous support formed simulta...