A genetic algorithm (GA) coupled with density functional theory (DFT) calculations is used to perform global optimisations for all compositions of 8-atom Au-Ag bimetallic clusters. The performance of this novel GA-DFT approach for bimetallic nanoparticles is tested for structures reported in the literature. New global minimum structures for various compositions are predicted and the 2D-3D trans...

Nanomaterials with particular nanostructures which usually possess special properties always attract considerable attention. A novel bimetallic Pt/Cu hexapod nanostructure was prepared by a facile one-pot strategy. The formation mechanism was investigated by the time sequential evolution experiments and the hexapod concave nanostructures originated from the Pt/Cu rhombic dodecahedron. Further e...

Herein we report the development of anisotropic bimetallic nanoparticles where aerosol gold nanoparticles served as the seeds for the continuous deposition of silver atoms on their surfaces. Initially, aerosol gold nanoparticles were formed by spark discharge and then injected into a silver precursor solution in an impinging device. The gold nanoparticles acted as the seed particles, and cataly...

Metal nanostructures have attracted great attention in various fields due to their tunable properties through precisely tailored sizes, compositions and structures. Using mesoporous silica (mSiO2) as the inorganic capping agent and encapsulated Pt nanoparticles as the seeds, we developed a robust seeded growth method to prepare uniform bimetallic nanoparticles encapsulated in mesoporous silica ...

Although the exchange coupling and local crystal-field environment are almost identical in the two-dimensional (2D) and three-dimensional (3D) series of bimetallic oxalates, those two classes of materials exhibit quite different magnetic properties. Using mean-field theory to treat the exchange interaction, we evaluate the transition temperatures and magnetizations of the 3D Fe(II)Fe(III) and M...

Binucleating multidentate amine bis(phenolate) ligands with rigid terphenyl backbones were designed to support two zirconium centers locked in close proximity. Polymerizations of propylene or 1-hexene with the synthesized bimetallic precatalysts resulted in polymers with significantly higher isotacticity (up to 79% mmmm) in comparison to the stereoirregular polymers produced with previously rep...

A strategy for the preparation of bimetallic mesoflowers (MFs) has been demonstrated by a simple overgrowth reaction. We make hybrid MFs containing Au core and shells of different metals, such as Ag and Pt, by tuning the experimental conditions so as to study region-specific overgrowth. This selective growth is attributed to the specific binding affinity of cetyltrimethylammonium bromide (CTAB)...

Water-soluble Ag-Au bimetallic nanostructures were prepared via co-reduction and seed-mediated growth routes employing poly-(4-styrenesulfonic acid-co-maleic acid) (PSSMA) as both a reductant and a stabilizer. Ag-Au alloy nanoparticles were obtained by the co-reduction of AgNO3 and HAuCl4, while Ag-Au core-shell nanostructures were prepared through seed-mediated growth using PSSMA-Au nanopartic...

A new class of bimetallic isopropoxides of nickel(II) with niobium and tantalum with the general formula, Ni[M(OPr')6]2, (where M = Nb or Ta) have been synthesized by the reaction of nickel chloride isopropanolate, NiCl2-A:Pr'OH, with potassium hexaisopropoxy metalates, KM(OPr')6, (M = Nb or Ta) in the molar ratio 1:2. These derivatives have been characterized by elemental analyses, molecular w...

Palladium/iron bimetallic nanoparticles were synthesized using microemulsion method in the water-in-oil (W/O) microemulsion system, which was made up of iso-octane, cetyltrimethyl-ammonium bromide (CTAB), butanol and water and characterized by measuring the conductivity of the solution. Transmission electron microscope (TEM) and energy dispersive X-ray microanalysis (EDX) analysis showed that t...