Photooxidation of alcohols to the corresponding aldehydes with a porphyrin/quinone/TEMPO (TEMPO=2,2,6,6-tetramethyl-1-piperidinyloxy free radical) system is described. This photoreaction is a combination of a photoinduced electron transfer from the porphyrin to the quinone and a TEMPO-catalyzed oxidation of alcohols triggered by one electron oxidation. The rates of oxidation were in the order o...

Herein, the synthesis, characterization and photocatalytic application of a novel hybrid polyoxometalate, which can absorb light in the visible region, are reported. This hybrid material was synthesized by attaching a monovacant polyoxometalate, (SiW11O39), through a (3-aminopropyl)triethoxysilane linker to the anthracene. The hybridization with anthracene drastically decreased the band gap of ...

Aerobic oxidation reactions have been the focus of considerable attention, but their use in mainstream organic chemistry has been constrained by limitations in their synthetic scope and by practical factors, such as the use of pure O(2) as the oxidant or complex catalyst synthesis. Here, we report a new (bpy)Cu(I)/TEMPO catalyst system that enables efficient and selective aerobic oxidation of a...

Herein we report that mixed zirconium-cerium-MOFs with amino-functionalized linkers (2-amino-1,4-benzenedicarboxylate, BDC-NH2, and 4-aminonaphthalene-2,6-dicarboxylate, NDC-NH2) act as effective non-noble-metal-based heterogeneous catalysts, for both the aerobic photooxidation of benzylic alcohols direct microwaves activation N-alkylation amines alcohols. The catalytic performance has been stu...

We report a synthetic platform for the formation of benzylic C–X bonds. Benzylboronic acid pinacol (Bpin) esters are useful intermediates but commercially uncommon, leading to preparations that typically rely upon stoichiometric metalation. Pd-catalyzed formal homologation arylboronic acids provides access these compounds that, in turn, allow C–C, C–O, and C–N bonds from Pd- Cu-mediated cross-c...