نتایج جستجو برای: benzo 15 crown 5
تعداد نتایج: 1577977 فیلتر نتایج به سال:
A new crown ether-POM (POM = polyoxometalate) adduct with the molecular formula [(C14H20O5)4(H3O)3]PMo12O40 · 0.5CH3CN (1) was isolated from the mixed solvent of acetonitrile and methanol. The adduct is constructed from Keggin [PMo12O40]3− anions and [(C14H20O5)(H3O)] and [(C14H20O5)2(H3O)] cations via electrostatic and hydrogen bonding interactions. The supramolecular interactions combine the ...
silica coated magnetite nanoparticles were covalent grafted with 3-aminopropyl trimethoxysilane to give aptscmnps. reaction of the resulted nanomaterial with 4-formyl benzo-12-crown-4 ether afforded fb12c4/aptsmnps nanocomposite material in which the crown ether moiety was attached through propyl chain spacer. characterization of the prepared nanocomposite was performed wit...
A benzo[b]quinolizinium-benzo-15-crown-5 ether conjugate 2a is presented that enables the fluorimetric detection of Mg(2+) and DNA by a significant light-up effect, along with a change of the emission wavelength with different analytes (Mg(2+): 495 nm; DNA: 550 nm). The mechanism of the excited-state deactivation of 2a was investigated by steady-state fluorescence spectroscopy in media of varie...
A novel luminescent chemosensor for detecting Hg(2+) with high selectivity, based on a pendant benzo crown ether terbium complex, has been designed and prepared.
2,4-dithiouracil (DTU) forms in the crystals the H-bonded monohydrates of a 1:1:1 ratio with 18-crown-6 (18C6) 1, cis,syn,cis-isomer of dicyclohexano-18-crown-6 (DCH6A) 2, and benzo-18-crown-6 (B18C6) 3, while the anhydrous adduct with cis,anti,cis-isomer of dicyclohexano-18-crown-6 (DCH6B) 4 is of a 2:1 ratio. In 1-3 the components reproducibly alternate in the chains, while in 4 the chains ar...
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