We provide the first in situ and real-time study of the effect of milling frequency on the course of a mechanochemical organic reaction conducted using a vibratory shaker (mixer) ball mill. The use of in situ Raman spectroscopy for real-time monitoring of the mechanochemical synthesis of a 2,3-diphenylquinoxaline derivative revealed a pronounced dependence of chemical reactivity on small variat...

The Diels–Alder reaction kinetics between diphenylfulvene and maleimide using mechanochemistry in liquid state is described. This was carried out solid a modified vibratory ball-mill with temperature control solution toluene as solvent. effect of temperature, ball mass, material, additives, aging were studied. We reported for the first time mechanochemical depending on ratio mass/mass reagent. ...

        Synthetic hydroxyapatite (HA) is the most helpful because of its similarity to natural bone in both crystalline structure and chemical composition. Recently, fluoridated hydroxyapatite (FHA) has been developed in dental and orthopedic application because it has lower solubility than pure HA, while maintaining the comparable bioactivity and biocompatibility. The aim of this study was to...

The Discrete Element Method (DEM) is attracting increasing interest for the simulation of industrial granular flows. While the majority of previous DEM modelling has considered two-dimensional flows, we present here a series of three-dimensional simulations for a number of important industrial applications. The charge motion in a 5 m diameter ball mill and in a Hicom nutating mill, discharge fr...

We demonstrate here using a disulfide system the first example of reversible, selective, and quantitative transformation between three crystalline polymorphs by ball mill grinding.

Natural Akermanite (NAM) has been successfully prepared by a modified sol-gel method. Optimization in calcination temperature and mechanical ball milling resulted in a pure and nano-sized powder which characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM) and Fourier transform infrared Spectroscopy (FT–IR). Calcium nitrate, ...

this study was performed to investigate the effects of refining on the mechanical and optical properties of waste newspaper. waste newspapers were prepared from gorgan ettelaat newspaper agency and were cut to 5 centimeter pieces, and then were soaked with sufficient distillated water. after 1 day fibers were separated by disintegrator and freeness values for each pulp before and after refining...