Engine knock is an undesired phenomenon in spark ignited internal combustion engines; such as a gasoline engine running the Otto cycle. Knocking originates from abnormal combustions at timings other than those decided by controlled ignition. Individual abnormal combustions of this type is also referred to as auto-ignition. Knocking is not only a limitation on engine efficiency and thus of envir...

A mixed proton–electron conducting perovskite was synthesized by liquid-citrate method and the corresponding membrane was prepared by pressing followed by sintering. The hydrogen permeability of BaCe0.9Yb0.1O3-δ was studied as a function of temperature and hydrogen partial pressure (PH2) gradient. Using 100% dry hydrogen at 1173 K, the hydrogen permeation rate of dense membranes (1.63 mm thick)...

A biased coinflip Ansatz provides a stochastic regional scale land surface climate model of minimum complexity, which represents physical and stochastic properties of an ideal rainfall–runoff chain. The solution yields the empirically derived Schreiber formula as an Arrhenius-type equation of state W = exp(-D). It is associated with two thresholds and combines river runoff Ro, precipitation P a...

The specific rates of solvolysis of isobutyl chloroformate (1) are reported at 40.0 °C and those for isobutyl chlorothioformate (2) are reported at 25.0 °C, in a variety of pure and binary aqueous organic mixtures with wide ranging nucleophilicity and ionizing power. For 1, we also report the first-order rate constants determined at different temperatures in pure ethanol (EtOH), methanol (MeOH)...

We derive an approximate energy barrier equation considering its adaptation to our model calculation employing the Néel-Arrhenius with Stoner-Wohlfarth grain or dot in magnetic recording. First, we calculate as a function of field by numerical for angle 0 180 deg between easy axis and field. This relation is represented 90 deg, taking account Pfeiffer’s approximation deg. Next, shape anisotropy...

The aim of this study was to evaluate the influence of the extra virgin olive oil (EVOO) physical state on the kinetics of oxidative reactions. To this purpose, EVOO was stored at increasing temperatures from 3 to 60 degrees C and the oxidation was followed by measuring both primary and secondary oxidation products. Results highlighted that crystallization plays an important role in determining...

Three competing mathematical fitting models (a point-by-point estimation method, a linear fit method, and an isoconversion method) of chemical stability (related substance growth) when using high temperature data to predict room temperature shelf-life were employed in a detailed comparison. In each case, complex degradant formation behavior was analyzed by both exponential and linear forms of t...