It is well known that volatiles such as water has significant influence on the properties of silicate melts. Carbon dioxide (CO2) also an abundant volatile in deep Earth, however effect CO2 polymerized melts, particularly transport properties, are poorly understood. This crucial for better understanding generation and migration carbon bearing magma crustal mantle settings. In this study, we exp...

The goal of this project is to examine the potential long term performance of the proposed aluminosilicate waste/storage form for the isolation and eventual direct disposal of the cesium and strontium separated from recycled nuclear fuel. In the first phase of this work, researchers will investigate the sintering procedure to prepare the drum-like aluminosilicate waste/storage form from the as-...

In this study, four Class F fly ashes were studied with a scanning electron microscope; the glassy phases were identified and their compositions quantified using point compositional analysis with k-means clustering and multispectral image analysis. The results showed that while the bulk oxide contents of the fly ashes were different, the four fly ashes had somewhat similar glassy phase composit...

Airborne fly ash from coal combustion may represent a source of bioavailable iron (Fe) in the open ocean. However, few studies have focused on Fe speciation and distribution in coal fly ash. In this study, chemical imaging of fly ash has been performed using a dual-beam focused ion beam/scanning electron microscope (FIB/SEM) system for a better understanding of how simulated atmospheric process...

Thin slices of white Portland cement-low calcium pulverized fuel ash (pfa) blended cement pastes containing 30 or 50% pfa were leached progressively in de-ionized water. The paste with 50% pfa was aged 13 years prior to leaching and those with 30% pfa were aged 1 and 13 years. Pastes were leached for up to 75 days and were characterized using thermal analysis, X-ray diffraction, analytical scan...

Density and hardness of glasses are known to increase upon both compression at the glass transition temperature (Tg) and ambient pressure sub-Tg annealing. However, a serial combination of the two methods does not result in higher density and hardness, since the effect of compression is countered by subsequent annealing and vice versa. In this study, we circumvent this by introducing a novel tr...

Aluminosilicate geopolymers with a high silica molar ratio have been prepared by mixing Croatian coal-ash (ASTM Class F) and sodium silicate solution (water glass, technical grade). The samples were cured at 85 °C for 8 h and 24 h in different experimental conditions. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM/EDS) have been use...