All‐solid‐state battery (ASSB) technology has emerged as a promising solution for developing safe and high‐energy‐density power sources. However, the pronounced interfacial charge transfer resistance between electrode solid electrolyte continues to be central obstacle in contemporary ASSBs. This work demonstrated first approach printing all‐solid‐state batteries by employing aerosol jet technol...

All-solid-state batteries (ASSBs) are promising to be next-generation battery that provides high energy density and intrinsic safety. Research in the field of ASSBs has so far focused on development highly conductive solid electrolytes (SEs). The commercialization requires well-established large-scale manufacturing for sulfide SEs with ionic conductivity. However, synthesis remains at laborator...

Dendrite growth is one of the leading factors that cause cycling deterioration for all-solid-state batteries (ASSBs). However, using a single dominant material to form solid electrolyte has encountered several setbacks due intrinsically competing in mechanics and electrochemistry. Inspired by “brick-and-mortar” structure, strategy embedding heterogeneous blocks (HBs) within (SE) proposed mitiga...

All-solid-state batteries have attracted wide attention for high-performance and safe batteries. The combination of solid electrolytes lithium metal anodes makes high-energy practical next-generation devices. However, when a electrolyte replaces the liquid electrolyte, many different interface/interphase issues arisen from contact with electrodes. Poor wettability unstable chemical/electrochemi...