Waste from tea, a beverage globally consumed is a common menace discarded to the environment thereby contributing to environmental pollution. The textile and paper industries have also been major culprits in the pollution of the environment through their indiscriminate discharge of dye solutions. These dyes are carcinogenic, mutagenic, and generally harmful to the entire eco-system; this has po...

Isothermal calorimetry operated in gas perfusion mode (IGPC) is often used to quantify the amorphous content of pharmaceutical powders. Typically, the calibration line is constructed using the heat of crystallisation as the sample is exposed to high levels of a plasticising vapour. However, since the physical form to which the amorphous fraction crystallises may be dependent on the presence of ...

Ergot alkaloids, in their active isomeric form, affect animal health and performance, and adsorbents are used to mitigate toxicities by reducing bioavailability. Adsorbents with high specificity (molecularly imprinted polymers: MIP) adsorb ergot alkaloids in vitro, but require evaluation for biological implications. Using ex vivo myography, synthetic polymers were evaluated for effects on the b...

Cylindrical adsorbers are usually used for pressure swing adsorption (PSA) processes. In this study, the flat-box adsorbers which stack together replaced the traditional cylindrical adsorbers. Simulation was performed for separation of air (21% oxygen; 79% nitrogen) in Skarstrom cycle. Instantaneous equilibrium between solid and gas phase with non-isothermal operation were assumed and the bed p...

Lysozyme-silica interactions and the resulting complexation were investigated through adsorption isotherms, dynamic and electrophoretic light scattering, circular dichroism (CD), and isothermal titration calorimetry (ITC). A thermodynamic analysis of ITC data revealed the existence of two binding modes during protein-nanoparticle complexation. Both binding modes are driven by the cooperation of...

Hydrogen storage is one of the most addressed issues in the green-economy field. The latest-discovered form of ice (XVII), obtained by application of an annealing treatment to a H2-filled ice sample in the C0-phase, could be inserted in the energy-storage context due to its surprising capacity of hydrogen physisorption, when exposed to even modest pressure (few mbars at temperature below 40 K),...

We study the interaction of alkali metal chlorides with lipid vesicles made of palmitoyloleoylphosphatidylcholine (POPC). An elaborate set of techniques is used to investigate the binding process at physiological conditions. The alkali cation binding to POPC is characterized thermodynamically using isothermal titration calorimetry. The isotherms show that for all ions in the alkali group the bi...

A series of sodium bentonite and thiamine were used as raw materials to prepare a new adsorbent – thiamine-modified bentonite. The adsorbent was applied in the pretreatment of pharmaceutical wastewater. The optimum preparation conditions of thiamine-modified bentonite were studied. The experiments showed that the removals of COD (chemical oxygen demand) reached 47.98 % under optimal condition. ...

in this study, a bacterial species which could remove lead from wastewater was isolated from lead contaminated soil prepared in the laboratory. based on the biochemical and morphological characterization the bacteria were identified as brevundimonas vesicularis. the biosorption potentiel of powdered dry biomass of b. vesicularis was investigated by batch adsorption experiments. it was found tha...

CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intens...