Scanning tunneling microscopy studies reveal that trace amounts of adsorbed S below a critical coverage on the order of 10 mML have little effect on the coarsening and decay of monolayer Ag adatom islands on Ag(111) at 300 K. In contrast, above this critical coverage, decay is greatly accelerated. This critical value appears to be determined by whether all S can be accommodated at step edges. A...

According to the Air Quality Framework Directive, air pollutant concentration levels have to be assessed and reported annually by each European Union member state, taking into consideration European air quality standards. Plans and programmes should be implemented in zones and agglomerations where pollutant concentrations exceed the limit and target values. The main objective of this study is t...

The sea breeze/land breeze circulation system in the Los Angeles a r ea results in transport of pollutants seaward at nigh t followed by return of aged material inland the next day . This characteristic wind reversal pattern both increases the r etention time available for the oxidation of S02 to form sulfates and causes individual a ir parcels to make mul tiple passes over large coas tal emiss...

A catalytic, enantioselective decarboxylative allylic alkylation of 4-thiopyranones is reported. The α-quaternary 4-thiopyranones produced are challenging to access by standard enolate alkylation owing to facile ring-opening β-sulfur elimination. In addition, reduction of the carbon-sulfur bonds provides access to elusive acyclic α-quaternary ketones. The alkylated products are obtained in up t...

Tremendous effort has been put into developing viable lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit significant capacity decay over cycling. Herein, we identify a new capacity fading mechanism of the sulfur cathodes, relating to Li(x)S deta...

Nitrogen-doped flexible carbon foam was used to fabricate a lithium sulfur battery. The stability and rate performance of the battery were evaluated. The battery with carbon foam calcined at 800 °C displayed superior stability compared with other tested batteries. Battery performance was closely related to the foam structure and component. However, good rate performance was achieved with the fo...

A highly diastereoselective cyclopropanation of cyclic enones with sulfur ylides was developed under catalyst-free conditions, producing multifunctional spirocyclopropanes in generally excellent yields (up to 99% yield and >99:1 d.r.). The asymmetric version of this method was realized by using an easily available chiral sulfur ylide, affording products with moderate to good stereoselectivity.

Joint Center for Energy Storage Research (JCESR), PNNL, Richland, WA, USA Physical and Computational Science Directorate, PNNL, Richland, WA, USA Energy and Environmental Directorate, PNNL, Richland, WA, USA Dept.Industrial & Manufacturing Engineering, Florida State University, Tallahassee, FL, USA Department of Chemical Engineering and Materials Science, University of California, Davis, CA, US...

Global change is impacting forests worldwide, threatening biodiversity and ecosystem services including climate regulation. Understanding how forests respond is critical to forest conservation and climate protection. This review describes an international network of 59 long-term forest dynamics research sites (CTFS-ForestGEO) useful for characterizing forest responses to global change. Within v...