250 words Introduction: 315 words Discussion: 950 words Abbreviations: HPLC, high performance liquid chromatography; LC-MS/MS, liquid chromatography/tandem mass spectrometry; RKIP, Raf1-kinase inhibitor protein; HEPES, 2-[4-(2-Hydroxyethyl)-1-piperazinyl]ethanesulfonic acid; DMSO, dimethylsulfoxide ; Tris, tris(hydroxymethyl)aminomethane, SDS-PAGE, sodium dodecyl sulfate-polyacrylamide gel elec...

A new bis cyclometallated Ir(III) phosphor, [Ir(ppy)2L]PF6 (ppy = 2-phenylpyridine, L 4,4?-bis(4-fluorophenyl)-6,6?-dimethyl-2,2?-bipyridine was prepared and structurally characterized in the solid state (X-ray diffraction) solution (1 2D NMR spectroscopy). The compound exhibited yellow photoluminescence (?em 562 nm). quantum yield ? solvent-dependent (5% acetonitrile 19% dichloromethane soluti...

250 words Introduction: 315 words Discussion: 950 words Abbreviations: HPLC, high performance liquid chromatography; LC-MS/MS, liquid chromatography/tandem mass spectrometry; RKIP, Raf1-kinase inhibitor protein; HEPES, 2-[4-(2-Hydroxyethyl)-1-piperazinyl]ethanesulfonic acid; DMSO, dimethylsulfoxide ; Tris, tris(hydroxymethyl)aminomethane, SDS-PAGE, sodium dodecyl sulfate-polyacrylamide gel elec...